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Bis(?-9-anthracenemethano-lato)bis-[dimethyl-aluminium(III)].

ABSTRACT: The title complex, [Al(2)(CH(3))(4)(C(15)H(11)O)(2)], is dimeric bridged through the O atoms of the 9-anthracenemethano-late anions. Each Al atom is tetra-coordinated by two bridging O atoms from two different 9-anthracenemethano-late ligands and by two C atoms from two methyl groups, forming a distorted tetra-hedral environment. The average Al-O bond distance in the Al(2)O(2) core is 1.845?Å.

SUBMITTER: Li CY

PROVIDER: S-EPMC2971356 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis(μ-9-anthracenemethano-lato)bis-[dimethyl-aluminium(III)].

Li Chen-Yu CY Lin Chia-Her CH Liu Yi-Chang YC Ko Bao-Tsan BT

Acta crystallographica. Section E, Structure reports online 20091007 Pt 11

The title complex, [Al(2)(CH(3))(4)(C(15)H(11)O)(2)], is dimeric bridged through the O atoms of the 9-anthracenemethano-late anions. Each Al atom is tetra-coordinated by two bridging O atoms from two different 9-anthracenemethano-late ligands and by two C atoms from two methyl groups, forming a distorted tetra-hedral environment. The average Al-O bond distance in the Al(2)O(2) core is 1.845 Å. ...[more]

PMID: 21578083

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