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Bis{2-(5-hydr-oxy-2-[1-(hydroxy-imino)eth-yl]phenolato-?O,N}nickel(II) N,N-dimethyl-formamide disolvate.

ABSTRACT: The Ni atom of the title complex, [Ni(C(8)H(8)NO(3))(2)]·2C(3)H(7)NO, lies on a center of inversion in a square-planar N(2)O(2) coordination environment. An intra-molecular O-H?O hydrogen bond exists between the oximic hydr-oxy group of one ligand and the metal-coordinated O atom of the symmetry-related ligand. The dimethyl-formamide solvent mol-ecules are connected to the phenolate groups of the complex via O-H?O hydrogen bonds.

SUBMITTER: Dang YQ

PROVIDER: S-EPMC2971387 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Bis{2-(5-hydr-oxy-2-[1-(hydroxy-imino)eth-yl]phenolato-κO,N}nickel(II) N,N-dimethyl-formamide disolvate.

Dang Yan-Qiu YQ

Acta crystallographica. Section E, Structure reports online 20091003 Pt 11

The Ni atom of the title complex, [Ni(C(8)H(8)NO(3))(2)]·2C(3)H(7)NO, lies on a center of inversion in a square-planar N(2)O(2) coordination environment. An intra-molecular O-H⋯O hydrogen bond exists between the oximic hydr-oxy group of one ligand and the metal-coordinated O atom of the symmetry-related ligand. The dimethyl-formamide solvent mol-ecules are connected to the phenolate groups of the complex via O-H⋯O hydrogen bonds. ...[more]

PMID: 21578069

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