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Trans-Bis[bis-(2-methoxy-phen-yl)phenyl-phosphine-?P]dichloridopalladium(II).

ABSTRACT: The structure of the title compound, [PdCl(2)(C(20)H(19)O(2)P)(2)], shows a square-planar geometry for the Pd(II) ion within a Cl(2)Pd[PPh(PhOMe)(2)](2) ligand set. The Pd(II) atom sits on an inversion centre and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom and one bis-(2-methoxy-phen-yl)phenyl-phosphine ligand. The trans arrangement of ligands is also imposed by symmetry.

SUBMITTER: van Blerk C

PROVIDER: S-EPMC2971441 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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trans-Bis[bis-(2-methoxy-phen-yl)phenyl-phosphine-κP]dichloridopalladium(II).

van Blerk Charmaine C Holzapfel Cedric W CW

Acta crystallographica. Section E, Structure reports online 20091010 Pt 11

The structure of the title compound, [PdCl(2)(C(20)H(19)O(2)P)(2)], shows a square-planar geometry for the Pd(II) ion within a Cl(2)Pd[PPh(PhOMe)(2)](2) ligand set. The Pd(II) atom sits on an inversion centre and therefore the asymmetric unit contains the Pd(II) atom, one Cl atom and one bis-(2-methoxy-phen-yl)phenyl-phosphine ligand. The trans arrangement of ligands is also imposed by symmetry. ...[more]

PMID: 21578097

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