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Catena-Poly[[bis-[(dicyanamido)silver(I)](Ag-Ag)]-?(2)-4,4'-bipyridine-?N:N'].

ABSTRACT: In the title compound, [Ag(2)(C(2)N(3))(2)(C(10)H(8)N(2))](n), the Ag atoms, lying on inversion centers, are separated by 3.3226?(12)?Å. Each Ag atom is connected by one bridging 4,4'-bipyridine [Ag-N = 2.177?(4)Å] and a terminal dicyanamide [Ag-N = 2.108?(4)?Å]. The Ag-Ag interactions play a key role in constructing a unique neutral polymeric chain.

SUBMITTER: Zhang J

PROVIDER: S-EPMC2972035 | biostudies-literature | 2009 Nov

REPOSITORIES: biostudies-literature

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catena-Poly[[bis-[(dicyanamido)silver(I)](Ag-Ag)]-μ(2)-4,4'-bipyridine-κN:N'].

Zhang Jinfang J

Acta crystallographica. Section E, Structure reports online 20091128 Pt 12

In the title compound, [Ag(2)(C(2)N(3))(2)(C(10)H(8)N(2))](n), the Ag atoms, lying on inversion centers, are separated by 3.3226 (12) Å. Each Ag atom is connected by one bridging 4,4'-bipyridine [Ag-N = 2.177 (4)Å] and a terminal dicyanamide [Ag-N = 2.108 (4) Å]. The Ag-Ag interactions play a key role in constructing a unique neutral polymeric chain. ...[more]

PMID: 21578705

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