Unknown

Dataset Information

0

Di-?-bromido-bis-[benz-yl(diethyl ether)magnesium].

ABSTRACT: The title benzyl Grignard reagent, [Mg(2)Br(2)(C(7)H(7))(2)(C(4)H(10)O)(2)], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-mol-ecule, the structural dimeric unit being generated by inversion symmetry with an Mg?Mg distance of 3.469?(2)?Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals inter-actions only.

SUBMITTER: Nesbit MA 

PROVIDER: S-EPMC3393201 | biostudies-literature | 2012 Jul

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

Di-μ-bromido-bis-[benz-yl(diethyl ether)magnesium].

Nesbit Mark A MA   Gray Danielle L DL   Girolami Gregory S GS  

Acta crystallographica. Section E, Structure reports online 20120620 Pt 7

The title benzyl Grignard reagent, [Mg(2)Br(2)(C(7)H(7))(2)(C(4)H(10)O)(2)], was obtained by reaction of benzyl bromide with magnesium in diethyl ether, followed by crystallization from toluene. The asymmetric unit comprises one half-mol-ecule, the structural dimeric unit being generated by inversion symmetry with an Mg⋯Mg distance of 3.469 (2) Å. The Mg(II) atom exhibits a distorted tetrahedral coordination geometry. The crystal packing is defined by van der Waals inter-actions only. ...[more]

Similar Datasets

Unknown Di-?-bromido-bis-[(diethyl ether-?O)(2,4,6-tri-methyl-phen-yl)magnesium]: the mesityl Grignard reagent.
| S-EPMC3772445 | biostudies-literature
Unknown Diethyl 2,2-bis-(3,5-di-tert-butyl-4-hy-droxy-benz-yl)malonate.
| S-EPMC3275203 | biostudies-literature
Unknown Bis(2-bromo-benz-yl) ether.
| S-EPMC4120549 | biostudies-literature
Unknown Di-?-iodido-bis-[(diethyl ether-?O)(?-1,3-di-tert-butyl-cyclo-penta-dien-yl)ytterbium(II)].
| S-EPMC2915154 | biostudies-literature
Unknown (Ethane-1,2-di-yl)bis-[bis-(3-methoxy-prop-yl)methyl-phospho-nium] bis-(tetra-phenyl-borate) diethyl ether solvate.
| S-EPMC2961532 | biostudies-literature
Unknown Bis[(4-bromo-benzoyl-meth-yl)triphenyl-phospho-nium] di-?-bromido-bis-[di-bromido-mercurate(IV)].
| S-EPMC2961466 | biostudies-literature
Unknown [N,N'-Bis(2,6-diethyl-4-phenyl-phen-yl)butane-2,3-di-imine-?(2) N,N']di-bromido-nickel(II).
| S-EPMC3998469 | biostudies-literature
Unknown Diethyl 3,4-bis-(2,5-dimethoxy-benz-yl)thieno[2,3-b]thio-phene-2,5-di-car-boxylate.
| S-EPMC2971147 | biostudies-literature
Unknown μ-Methyl-ene-bis-[di-bromido(diethyl ether-κ<i>O</i>)aluminium(III)]: crystal structure and chemical exchange in solution.
| S-EPMC8183446 | biostudies-literature
Unknown Di-?-hydroxido-bis-[aqua-trichlorido-tin(IV)] diethyl ether disolvate.
| S-EPMC2959587 | biostudies-literature