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1,4-Diazo-niabicyclo-[2.2.2]octane diaqua-dichlorido-(oxalato-?O,O')iron(III) chloride.

ABSTRACT: In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol-ecules and two chloride anions in a distorted octa-hedral geometry. Inter-molecular N-H?O, O-H?O and O-H?Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing.

SUBMITTER: Cai Y

PROVIDER: S-EPMC2977407 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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1,4-Diazo-niabicyclo-[2.2.2]octane diaqua-dichlorido-(oxalato-κO,O')iron(III) chloride.

Cai Ying Y

Acta crystallographica. Section E, Structure reports online 20090708 Pt 8

In the title compound, (C(6)H(14)N(2))[Fe(C(2)O(4))Cl(2)(H(2)O)(2)]Cl, all ions are situated on twofold rotational axes. The Fe(III) ion is coordinated by two O atoms from a chelating oxalate ligand, two water mol-ecules and two chloride anions in a distorted octa-hedral geometry. Inter-molecular N-H⋯O, O-H⋯O and O-H⋯Cl hydrogen bonds form an extensive three-dimensional network which consolidates the crystal packing. ...[more]

PMID: 21583342

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