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Catena-Poly[dipropyl-ammonium [[bis-(benzotriazolato-?N)zinc(II)]-?-benzotriazolato-?N:N]].

ABSTRACT: In the title compound, {(C(6)H(16)N)[Zn(C(6)H(4)N(3))(3)]}(n), the Zn(II) atom has a distorted tetra-hedral geometry defined by four N atoms from four benzotriazolate (BTA) ligands. The compound is composed of extended polymeric chains in which two BTA N atoms bridge [Zn(BTA)(2)] fragments along [001]. Cations and anions are linked by N-H?N hydrogen-bond inter-actions along [010].

SUBMITTER: Xu L

PROVIDER: S-EPMC2977513 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

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catena-Poly[dipropyl-ammonium [[bis-(benzotriazolato-κN)zinc(II)]-μ-benzotriazolato-κN:N]].

Xu Liping L

Acta crystallographica. Section E, Structure reports online 20090708 Pt 8

In the title compound, {(C(6)H(16)N)[Zn(C(6)H(4)N(3))(3)]}(n), the Zn(II) atom has a distorted tetra-hedral geometry defined by four N atoms from four benzotriazolate (BTA) ligands. The compound is composed of extended polymeric chains in which two BTA N atoms bridge [Zn(BTA)(2)] fragments along [001]. Cations and anions are linked by N-H⋯N hydrogen-bond inter-actions along [010]. ...[more]

PMID: 21583348

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