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(2,9-Dimethyl-1,10-phenanthroline-?N,N')diiodidocadmium.


ABSTRACT: In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol-ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra-hedral geometry. Inversion-related mol-ecules inter-act along the c-axis direction by ?-? stacking inter-actions between the phenanthroline ring systems, with centroid-centroid distances of 3.707?(9) and 3.597?(10)?Å.

SUBMITTER: Warad I 

PROVIDER: S-EPMC3238587 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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(2,9-Dimethyl-1,10-phenanthroline-κN,N')diiodidocadmium.

Warad Ismail I   Boshaala Ahmed A   Al-Resayes Saud I SI   Al-Deyab Salem S SS   Rzaigui Mohamed M  

Acta crystallographica. Section E, Structure reports online 20111102 Pt 12


In the title compound, [CdI(2)(C(14)H(12)N(2))], the mol-ecule sits on a crystallographic twofold axis. The coordination sphere of the Cd(II) atom is built of two symmetry-equivalent N atoms of one 2,9-dimethyl-1,10-phenanthroline (dmphen) ligand and two symmetry-equivalent I atoms, thus forming a distorted tetra-hedral geometry. Inversion-related mol-ecules inter-act along the c-axis direction by π-π stacking inter-actions between the phenanthroline ring systems, with centroid-centroid distance  ...[more]

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