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Catena-Poly[heptyl-enedi-ammonium [[tetra-chloridobismuthate(III)]-?-chlorido]].

ABSTRACT: The title organic-inorganic hybrid compound, {(C7H20N2)[BiCl5]} n , consists of distorted corner-joined [BiCl6] octa-hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl-enedi-ammonium cations. The asymmetric unit contains two crystallographically independent bis-muth metal atoms, one of which lies on an inversion centre and the other on a twofold axis. In the crystal, the polymeric chains and cations are linked by N-H?Cl hydrogen bonds, forming undulating layers parallel to (110).

SUBMITTER: Ouasri A

PROVIDER: S-EPMC3793680 | biostudies-literature | 2013

REPOSITORIES: biostudies-literature

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catena-Poly[heptyl-enedi-ammonium [[tetra-chloridobismuthate(III)]-μ-chlorido]].

Ouasri Ali A Rhandour Ali A Saadi Mohamed M El Ammari Lahcen L

Acta crystallographica. Section E, Structure reports online 20130706 Pt 8

The title organic-inorganic hybrid compound, {(C7H20N2)[BiCl5]} n , consists of distorted corner-joined [BiCl6] octa-hedra forming zigzag polymeric anionic chains parallel to [001], separated by columns of heptyl-enedi-ammonium cations. The asymmetric unit contains two crystallographically independent bis-muth metal atoms, one of which lies on an inversion centre and the other on a twofold axis. In the crystal, the polymeric chains and cations are linked by N-H⋯Cl hydrogen bonds, forming undulat ...[more]

PMID: 24109267

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