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Catena-Poly[[[pyridinecopper(II)]-(?-2-oxidonaphthalene-1-carbaldehyde pico-linoylhydrazonato)-[pyridinecopper(II)]-?-sulfato] diethyl ether hemisolvate].

ABSTRACT: The title compound, {[Cu(2)(C(17)H(11)N(3)O)(SO(4))(C(5)H(5)N)(2)]·0.5C(4)H(10)O}(n), was syn-thesized by the reaction of 2-hydr-oxy-1-naphthyl-aldehyde-2-pyridine-carboxyl-hydrazone with copper sulfonate. A one-dimensional polymer was obtained via self-assembly. Each Cu ion is located in a distorted square-pyramidal coordination environment, with one Cu ion coordinated by two N and three O atoms, while the other links to two O and three N atoms. In the crystal, weak inter-molecular C-H?O inter-actions connect the chains into a two-dimensional network.

SUBMITTER: Wang Q

PROVIDER: S-EPMC2977577 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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catena-Poly[[[pyridinecopper(II)]-(μ-2-oxidonaphthalene-1-carbaldehyde pico-linoylhydrazonato)-[pyridinecopper(II)]-μ-sulfato] diethyl ether hemisolvate].

Wang Quanchang Q Li Dacheng D Wang Daqi D

Acta crystallographica. Section E, Structure reports online 20090418 Pt 5

The title compound, {[Cu(2)(C(17)H(11)N(3)O)(SO(4))(C(5)H(5)N)(2)]·0.5C(4)H(10)O}(n), was syn-thesized by the reaction of 2-hydr-oxy-1-naphthyl-aldehyde-2-pyridine-carboxyl-hydrazone with copper sulfonate. A one-dimensional polymer was obtained via self-assembly. Each Cu ion is located in a distorted square-pyramidal coordination environment, with one Cu ion coordinated by two N and three O atoms, while the other links to two O and three N atoms. In the crystal, weak inter-molecular C-H⋯O inter- ...[more]

PMID: 21583763

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catena-Poly[[[tetra-kis-(4-methyl-pyridine-κN)copper(II)]-μ-sulfato-κO:O'] 4.393-hydrate].

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