Browse
Submit Data
Databases
API
Help

Dataset Information

28 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Catena-Poly[[aqua-glycolatocopper(II)]-?-chlorido].

ABSTRACT: In the crystal structure of the title compound, [Cu(C(2)H(3)O(3))Cl(H(2)O)](n), the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. Two O atoms from a chelating glycolate anion, an O atom from a coordinated water mol-ecule and a chloride anion comprise the basal plane. A chloride ion from a neighbouring unit occupies the apical position and these Cu-Cl-Cu bridges link the aqua-glycolatocopper(II) units into one-dimensional chains along the [001] direction. These chains are connected by O-H?O and O-H?Cl hydrogen bonds, forming an infinite three-dimensional polymeric network.

SUBMITTER: Fun HK

PROVIDER: S-EPMC2961558 | biostudies-literature | 2008 May

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

catena-Poly[[aqua-glycolatocopper(II)]-μ-chlorido].

Fun Hoong-Kun HK John Jain J Jebas Samuel Robinson SR Balasubramanian T T

Acta crystallographica. Section E, Structure reports online 20080503 Pt 6

In the crystal structure of the title compound, [Cu(C(2)H(3)O(3))Cl(H(2)O)](n), the Cu(II) ion is five-coordinate in a distorted square-pyramidal geometry. Two O atoms from a chelating glycolate anion, an O atom from a coordinated water mol-ecule and a chloride anion comprise the basal plane. A chloride ion from a neighbouring unit occupies the apical position and these Cu-Cl-Cu bridges link the aqua-glycolatocopper(II) units into one-dimensional chains along the [001] direction. These chains ar ...[more]

PMID: 21202446

Similar Datasets

catena-Poly[[chlorido(methyl phenyl sulfide-?S)mercury(II)]-?-chlorido].

Project description:The title compound, [HgCl(2)(C(7)H(8)S)](n), was isolated from the reaction of MeSPh with HgCl(2). The Hg(II) atom has a distorted tetra-hedral geometry and is coordinated by one S atom and three Cl atoms. Two of the Cl atoms act as bridging ligands between the Hg atoms, forming a two-dimensional polymeric structure.

| S-EPMC2961523 | biostudies-literature

catena-Poly[bis-(sulfamethoxazolium) [[trichloridocadmate(II)]-?-chlorido] monohydrate].

Project description:In the title compound, {(C(10)H(12)N(3)O(3)S)(2)[CdCl(4)]·H(2)O}(n), the Cd(II) atom is five-coordinate with a distorted trigonal-bipyramidal geometry formed by chloride ions. The Cd atom and two of the Cl atoms lie on a mirror plane. The cation is protonated on the amino group N atom; it is not coordinated to cadmium, but is hydrogen bonded to the chlorido ligands. Each water mol-ecule bridges two chlorido ligands, generating ring motifs along the -Cd-Cl-Cd- chains. The isoxazole unit and the amide groups are linked through a pair of N-H?N hydrogen bonds. The crystal structure is stabilized by N-H?O, O-H?Cl, C-H?N, N-H?Cl and C-H?O hydrogen bonds.

| S-EPMC2915166 | biostudies-literature

catena-Poly[[aqua-dipyridine-copper(II)]-μ-fumarato].

Project description:The title compound, [Cu(C(4)H(2)O(4))(C(5)H(5)N)(2)(H(2)O)](n), is a one-dimensional coordination polymer based on pyridine and fumarate ligands. Each Cu(II) cation is coordinated by two carboxyl-ate O atoms belonging to two fumarate anions, two N atoms from two pyridine mol-ecules and one water mol-ecule, in a square-based pyramidal geometry. Each fumarate anion bridges two Cu(II) cations through the two carboxyl-ate groups in a bis-monodentate fashion to form a one-dimensional polymeric chain along the c axis. Neighbouring chains are linked together to form a two-dimensional network parallel to the ac plane via hydrogen bonding inter-actions between uncoordinated carboxyl-ate O atoms and coordinated water mol-ecules of adjecent chains.

| S-EPMC2914965 | biostudies-literature

catena-Poly[2-methyl-1H-imidazol-3-ium [(aqua-chloridocadmate)-di-μ-chlorido]].

Project description:The asymmetric unit of the title compound, {(C(4)H(7)N(2))[CdCl(3)(H(2)O)]}(n), contains one 1-methyl-1H-imidazol-3-ium cation, one Cd(II) atom, three Cl atoms and one water mol-ecule. Adjacent Cd ions are inter-connected alternately by paired Cl(-) bridges to generate an infinite one-dimensional coordination chain along the b axis. In the chain, the crystallographically unique Cd(II) atom, with a distorted octa-hedral geometry, is coordinated by five Cl(-) ions and one water mol-ecule. Intra-chain O-H⋯Cl hydrogen bonding and N-H⋯Cl hydrogen bonding between the cations and the anionic chains consolidate the crystal packing.

| S-EPMC3246997 | biostudies-literature

catena-Poly[trimethyl-phenyl-ammonium [[bromidocad-mate(II)]-?-bromido-?-chlorido]].

Project description:In the title salt, (C(9)H(14)N)[CdBr(2)Cl], the Cd(II) atom is five-coordinated in a trigonal-bipyramidal coordination environment. All three of the halogen sites show disorder as a result of substitution of Cl for Br or Br for Cl. Two of the three halogen atoms are involved in bridging a pair of Cd(II) atoms, generating a linear polyanionic chain motif.

| S-EPMC2983584 | biostudies-literature

catena-Poly[[chloridomercury(II)]-?-1,4-diaza-bicyclo-[2.2.2]octane-?N:N'-[chlorido-mercury(II)]-di-?-chlorido].

Project description:In the title coordination polymer, [Hg(2)Cl(4)(C(6)H(12)N(2))](n), each Hg(II) center within the chain is four-coordinated by one terminal Cl atom, two bridging ?(2)-Cl atoms, and one N-atom donor from a ?(2)-1,4-diaza-bicyclo-[2.2.2]octane (?(2)-daco) ligand in a distorted tetra-hedral geometry. The daco ligand acts as an end-to-end bridging ligand and bridges adjacent Hg(II) centers, forming a chain running along [001]. Weak C-H?Cl hydrogen-bonding inter-actions link the chains into a three-dimensional network. Comparison of the structural differences with previous findings suggests that the space between the two N donors, as well as the skeletal rigidity in N-heterocyclic linear ligands, may play an important role in the construction of such supra-molecular networks.

| S-EPMC2971285 | biostudies-literature

Crystal structure of catena-poly[1,3-di-benzyl-benzimidazolium [[chlorido-mercurate(II)]-di-?-chlorido]].

Project description:The asymmetric unit of the polymeric title compound, {(C21H19N2)[HgCl3]} n , comprises one-half of the cationic mol-ecule, the other half being generated by application of twofold rotation symmetry, one Hg and two Cl atoms. The Hg(II) atom, lying on a twofold rotation axis, exhibits a distorted triangular coordination environment and is surrounded by three Cl atoms with Hg-Cl distances in the range 2.359?(2)-2.4754?(13)?Å. Two additional longer distances [Hg?Cl = 3.104?(14)?Å] lead to the formation of polymeric [HgCl1/1Cl4/2](-) chains extending along [001]. The crystal packing can be described by cationic layers alternating parallel to (-110) with the anionic chains located between the layers. The packing is consolidated by ?-? stacking inter-actions between the benzene rings of the central benzimidazole entities, with centroid-to-centroid distances of 3.643?(3)?Å.

| S-EPMC4719861 | biostudies-literature

catena-Poly[[[tetra-aqua-iron(II)]-?-5,5'-diazenediylditetra-zolido] dihydrate].

Project description:In the title compound, {[Fe(C(2)N(10))(H(2)O)(4)]·2H(2)O}(n), the coordin-ation geometry around the Fe(II) atom, which lies on a center of inversion, is distorted octa-hedral, with bonds to four O atoms and two N atoms. The azotetra-zolate ligand displays a bridging coordination mode, forming an infinite zigzag chain. Inter-molecular O-H?O and O-H?N hydrogen bonding and offset face-to-face ?-? stacking inter-actions [centroid-centroid distance = 3.4738?(13)?Å] lead to a three-dimensional network.

| S-EPMC3009247 | biostudies-literature

catena-Poly[[tetra-aqua-copper(II)]-?-tri-thionato-?O:O'].

Project description:The title supra-molecular polymer, [Cu(S(3)O(6))(H(2)O)(4)](n), features a tetra-gonally distorted octa-hedral Cu(II) centre within an O(6) donor set with the longer Cu-O bonds linking the dication and the trithio-nate dianion. Extensive O-H?O hydrogen-bonding inter-actions connect the supra-molecular chains into a three-dimensional network.

| S-EPMC2972059 | biostudies-literature

catena-Poly[[aqua-bromidocopper(II)]-μ(3)-(picolinato N-oxide)].

Project description:The title complex, [CuBr(C(6)H(4)NO(3))(H(2)O)](n), exhibits a layered structure which is stabilized by inter-molecular O-H⋯O and O-H⋯Br(-) hydrogen bonds, van der Waals forces and π-π inter-actions [centroid-centroid distance = 3.747(4) Å] between the parallel pyridine rings from two neighboring layers.

| S-EPMC3051695 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data