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Catena-Poly[[[diiodidocadmium(II)]-?-1-(4-pyridylmeth-yl)-1H-benzimidazole] methanol hemisolvate].

ABSTRACT: In the title coordination polymer, {[CdI(2)(C(13)H(11)N(3))]·0.5CH(4)O}(n), each Cd(II) center is four-coordinated by two N-atom donors from two 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two iodide anions, forming a tetra-hedral coordination geometry. L ligands bridge adjacent Cd(II) ions, generating two crystallographically independent approximately orthogonal one-dimensional chains. The methanol solvent mol-ecule associates with one of the chains via O-H?I inter-actions.

SUBMITTER: Wang JJ

PROVIDER: S-EPMC2915130 | biostudies-literature | 2007 Dec

REPOSITORIES: biostudies-literature

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catena-Poly[[[diiodidocadmium(II)]-μ-1-(4-pyridylmeth-yl)-1H-benzimidazole] methanol hemisolvate].

Wang Jun-Jie JJ Yan Li-Fan LF Hu Tong-Liang TL

Acta crystallographica. Section E, Structure reports online 20071218 Pt 1

In the title coordination polymer, {[CdI(2)(C(13)H(11)N(3))]·0.5CH(4)O}(n), each Cd(II) center is four-coordinated by two N-atom donors from two 1-(4-pyridylmeth-yl)-1H-benzimidazole (L) ligands and two iodide anions, forming a tetra-hedral coordination geometry. L ligands bridge adjacent Cd(II) ions, generating two crystallographically independent approximately orthogonal one-dimensional chains. The methanol solvent mol-ecule associates with one of the chains via O-H⋯I inter-actions. ...[more]

PMID: 21200548

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