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Bis[4-methyl-2-(4-methyl-phenyldiazen-yl)phenolato-?N,O]nickel(II).

ABSTRACT: In the crystal structure of the title compound, [Ni(C(14)H(13)N(2)O)(2)], the Ni(II) ion is located on an inversion center and is coordinated by two 4-methyl-2-(4-methyl-phenyl-diazen-yl)phenolate anions in a slightly distorted square-planar geometry. Within the anion, the two benzene rings are twisted from each other with a dihedral angle of 45.97?(12)°. No hydrogen bonding is found in the crystal structure.

SUBMITTER: Guan D

PROVIDER: S-EPMC2977611 | biostudies-literature | 2009 Apr

REPOSITORIES: biostudies-literature

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Bis[4-methyl-2-(4-methyl-phenyldiazen-yl)phenolato-κN,O]nickel(II).

Guan Dexin D Sun Hongjian H

Acta crystallographica. Section E, Structure reports online 20090425 Pt 5

In the crystal structure of the title compound, [Ni(C(14)H(13)N(2)O)(2)], the Ni(II) ion is located on an inversion center and is coordinated by two 4-methyl-2-(4-methyl-phenyl-diazen-yl)phenolate anions in a slightly distorted square-planar geometry. Within the anion, the two benzene rings are twisted from each other with a dihedral angle of 45.97 (12)°. No hydrogen bonding is found in the crystal structure. ...[more]

PMID: 21583797

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