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Poly[[(?(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate].

ABSTRACT: In the title compound, {[Cu(C(18)H(12)N(6))]NO(3)·H(2)O}(n), the Cu(I) ion is coordinated by three N atoms [Cu-N 1.962?(3)-2.019?(3)?Å] from three 2,4,6-tri-4-pyridyl-1,3,5-triazine (L) ligands. Each L ligand bridges three Cu(I) atoms, generating a positively charged three-dimensional polymeric network with voids propagated along the b axis. These voids are filled with NO(3) (-) anions with a shortest Cu?O distance of 2.645?(3)?Å and water mol-ecules, which are linked into negatively charged helical chains via inter-molecular O-H?O hydrogen bonds.

SUBMITTER: Feng M

PROVIDER: S-EPMC3099806 | biostudies-other | 2011 Apr

REPOSITORIES: biostudies-other

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Poly[[(μ(3)-2,4,6-tri-4-pyridyl-1,3,5-triazine)copper(I)] nitrate monohydrate].

Feng Miao M Tian Hui-Juan HJ Mi Huai-Feng HF Hu Tong-Liang TL

Acta crystallographica. Section E, Structure reports online 20110331 Pt 4

In the title compound, {[Cu(C(18)H(12)N(6))]NO(3)·H(2)O}(n), the Cu(I) ion is coordinated by three N atoms [Cu-N 1.962 (3)-2.019 (3) Å] from three 2,4,6-tri-4-pyridyl-1,3,5-triazine (L) ligands. Each L ligand bridges three Cu(I) atoms, generating a positively charged three-dimensional polymeric network with voids propagated along the b axis. These voids are filled with NO(3) (-) anions with a shortest Cu⋯O distance of 2.645 (3) Å and water mol-ecules, which are linked into negatively charged hel ...[more]

PMID: 21754019

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