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[N,N'-Bis(2,6-diisopropyl-phen-yl)pentane-2,4-diamine-(1-)-2?N,N']-?(2)-chlorido-1:2?Cl:Cl-chlorido-2?Cl-bis-(1,2-di-methoxy-ethane-1?O,O')iron(II)lithium.

ABSTRACT: In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra-hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy-ethane mol-ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034?Å.

SUBMITTER: Grubba R

PROVIDER: S-EPMC2979477 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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[N,N'-Bis(2,6-diisopropyl-phen-yl)pentane-2,4-diamine-(1-)-2κN,N']-μ(2)-chlorido-1:2κCl:Cl-chlorido-2κCl-bis-(1,2-di-methoxy-ethane-1κO,O')iron(II)lithium.

Grubba Rafał R Ponikiewski Lukasz L Tomorowicz Lukasz L Pikies Jerzy J

Acta crystallographica. Section E, Structure reports online 20100526 Pt 6

In the title compound, [FeLi(C(29)H(41)N(2))Cl(2)(C(4)H(10)O(2))(2)], the Fe(II) atom is coordinated by two N and two Cl atoms, generating a distorted FeN(2)Cl(2) tetra-hedral geometry. Additionally, one of the chloride atoms bridges to a lithium ion, which is solvated by two dimethoxy-ethane mol-ecules and is coordinated in a distorted trigonal-bipyramidal environment. The central Fe, Cl (× 2) and Li atoms are coplanar with a maximum deviation of 0.034 Å. ...[more]

PMID: 21579340

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Bis[N,N'-bis-(2,6-diisopropyl-phen-yl)ethane-1,2-diimine]-1?N,N';2?N,N'-tri-?-trichlorido-1:2?Cl:Cl-chlorido-1?Cl-tetra-hydro-furan-2?O-dichromium(II) dichloro-methane 4.5-solvate.

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