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Bis(acetato-?O)[1,2-bis-(2-pyridylmeth-oxy)benzene-?N,O,O',N']copper(II) monohydrate.

ABSTRACT: In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·H(2)O, the Cu(II) ion is six-coordinated in a typically Jahn-Teller distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from acetate anions. A linear chain structure propagating in [010] is built up by inter-molecular O-H?O hydrogen bonds involving the uncoordinated water mol-ecules.

SUBMITTER: Zhang S

PROVIDER: S-EPMC2979615 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Bis(acetato-κO)[1,2-bis-(2-pyridylmeth-oxy)benzene-κN,O,O',N']copper(II) monohydrate.

Zhang Shuang S Wang Yu-Jie YJ Ma Dong-Sheng DS Liu Ying Y Gao Jin-Sheng JS

Acta crystallographica. Section E, Structure reports online 20100522 Pt 6

In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·H(2)O, the Cu(II) ion is six-coordinated in a typically Jahn-Teller distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from acetate anions. A linear chain structure propagating in [010] is built up by inter-molecular O-H⋯O hydrogen bonds involving the uncoordinated water mol-ecules. ...[more]

PMID: 21579336

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Bis(acetato-?O)[1,2-bis-(2-pyridyl-meth-oxy)benzene-?N,O,O',N']copper(II) tetra-hydrate.

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