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Bis(acetato-?O)[1,2-bis-(2-pyridylmeth-oxy)benzene-?N,O,O',N']copper(II) monohydrate.

ABSTRACT: In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·H(2)O, the Cu(II) ion is six-coordinated in a typically Jahn-Teller distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from acetate anions. A linear chain structure propagating in [010] is built up by inter-molecular O-H?O hydrogen bonds involving the uncoordinated water mol-ecules.

SUBMITTER: Zhang S

PROVIDER: S-EPMC2979615 | biostudies-literature | 2010 May

REPOSITORIES: biostudies-literature

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Bis(acetato-κO)[1,2-bis-(2-pyridylmeth-oxy)benzene-κN,O,O',N']copper(II) monohydrate.

Zhang Shuang S Wang Yu-Jie YJ Ma Dong-Sheng DS Liu Ying Y Gao Jin-Sheng JS

Acta crystallographica. Section E, Structure reports online 20100522 Pt 6

In the title compound, [Cu(CH(3)COO)(2)(C(18)H(16)N(2)O(2))]·H(2)O, the Cu(II) ion is six-coordinated in a typically Jahn-Teller distorted octa-hedral environment defined by two O and two N atoms from the ligand and two O atoms from acetate anions. A linear chain structure propagating in [010] is built up by inter-molecular O-H⋯O hydrogen bonds involving the uncoordinated water mol-ecules. ...[more]

PMID: 21579336

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Bis(acetato-?O)[1,2-bis-(2-pyridyl-meth-oxy)benzene-?N,O,O',N']copper(II) tetra-hydrate.

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1,4-Bis(4-pyridylmeth-oxy)benzene.

Project description:The mol-ecule of the title compound, C(18)H(16)N(2)O(2), lies about a center of inversion. The central phenyl-ene ring is aligned at 62.7?(1)° with respect to the pyridyl ring. In the crystal, weak inter-molecular C-H?N hydrogen bonds link mol-ecules into sheets parallel to (104). C-H?O inter-actions are also present.

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Bis(acetato-?O)bis-(4,5-dimethyl-benzene-1,2-diamine-?N)zinc.

Project description:The structure of the title compound, [Zn(CH(3)COO)(2)(C(8)H(12)N(2))(2)], has one half molecule in the asymmetric unit. The Zn(II) atom is situated on a twofold rotation axis and is tetrahedrally coordinated by two N and two O atoms. The crystal packing displays inter-molecular N-H?O hydrogen bonds and intra-molecular N-H?O and N-H?N hydrogen bonding.

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Project description:In the crystal structure of the title compound, [Cu(C(12)H(9)O(2))(2)(C(4)H(6)N(2))(2)]·H(2)O, the Cu(II) atom is coordinated by two 2-(naphthalen-1-yl)acetate anions and two 1-methyl-imidazole ligands, giving monomeric complexes with a square-planar coordination environment. Two complex mol-ecules and two water mol-ecules form a centrosymmetric ring system via O-H?O hydrogen bonds.

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