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Di-?-ethano-lato-bis-[diethano-lato(2-methyl-quinolin-8-olato)titanium(IV)].

ABSTRACT: In the centrosymmetric dinuclear title compound, [Ti(2)(C(10)H(8)NO)(2)(C(2)H(5)O)(6)], the Ti atom is bonded to an N,O-bidentate quinolin-8-olate ligand, two terminal ethano-late anions and two bridging ethano-late anions in a distorted TiNO(5) octa-hedral geometry. An intra-molecular C-H?O hydrogen bond occurs; in the crystal, inter-molecular C-H?O inter-actions help to establish the packing.

SUBMITTER: Fazaeli Y

PROVIDER: S-EPMC2971800 | biostudies-other | 2009

REPOSITORIES: biostudies-other

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Di-μ-ethano-lato-bis-[diethano-lato(2-methyl-quinolin-8-olato)titanium(IV)].

Fazaeli Yousef Y Najafi Ezzatollah E Amini Mostafa M MM Khavasi Hamid Reza HR

Acta crystallographica. Section E, Structure reports online 20091107 Pt 12

In the centrosymmetric dinuclear title compound, [Ti(2)(C(10)H(8)NO)(2)(C(2)H(5)O)(6)], the Ti atom is bonded to an N,O-bidentate quinolin-8-olate ligand, two terminal ethano-late anions and two bridging ethano-late anions in a distorted TiNO(5) octa-hedral geometry. An intra-molecular C-H⋯O hydrogen bond occurs; in the crystal, inter-molecular C-H⋯O inter-actions help to establish the packing. ...[more]

PMID: 21578574

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