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(μ-2,3-Dihydroxy-butane-1,4-dithiol-ato)bis-[triphenyl-tin(IV)].

ABSTRACT: In the title compound, [Sn(2)(C(6)H(5))(6)(C(4)H(8)O(2)S(2))], the geometry around the Sn atoms is distorted tetra-hedral. The hydr-oxy groups are involved in O-H⋯O hydrogen bonding, which connects mol-ecules into centrosymmetric dimers.

SUBMITTER: Li C

PROVIDER: S-EPMC2979966 | biostudies-literature |

REPOSITORIES: biostudies-literature

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(Ferrocene-carboxyl-ato-κO)triphenyl-tin(IV).

Project description:In the title compound, [FeSn(C(5)H(5))(C(6)H(5))(3)(C(6)H(4)O(2))], the Sn(IV) atom displays a distorted tetra-hedral coordination geometry, provided by one O atom of the monodentate ferrocene-carboxyl-ate ligand [Sn-O = 2.079 (2) Å] and by three C atoms of the three phenyl groups [average Sn-C = 2.130 (4) Å]. No classic hydrogen bonds or inter-molecular inter-actions are observed in the crystal.

| S-EPMC3006984 | biostudies-literature

catena-Poly[triethyl-ammonium [[triphenyl-tin(IV)]-?-3,3'-dihydroxy-4,4'-methyl-ene-di-2-naphtho-ato]].

Project description:The title compound, {(C(6)H(16)N)[Sn(C(6)H(5))(3)(C(23)H(14)O(6))]}(n), has an infinite chain structure, formed through monodentate carboxyl-ate groups of the pamoic acid anion. The anion bridges two symmetry-related Sn(IV) ions and the resulting polymeric chains are parallel to [201] in the crystal. Et(3)NH(+) cations are inserted between the chains. The coordination of the Sn(IV) atom is completed by three phenyl ligands, giving a distorted trigonal-bipyramidal geometry.

| S-EPMC3050292 | biostudies-other

Bis(triethyl-ammonium) bis-(μ-pyrazine-2,3-dithiol-ato)bis-(pyrazine-2,3-dithio-lato)diferrate(III) methanol disolvate.

Project description:In the title compound, (C(6)H(16)N)(2)[Fe(2)(C(4)H(2)N(2)S(2))(4)]·2CH(4)O, the [Fe(III)(pdt)(2)](-) anion (pdt is pyrazine-2,3-dithiol-ate) forms a centrosymmetric dimer supported by two Fe(III)-S bonds [Fe-S = 2.4787 (4) Å]. In the crystal structure, dimers form a one-dimensional stack along the b axis via π-π stacking inter-actions, the inter-planar separation between adjacent dimers being 3.51 (2) Å. The methanol solvent mol-ecule is involved in two hydrogen bonds in which the hydroxyl group acts as a hydrogen-bond donor to the N atom of a pdt ligand and the O atom acts as an acceptor for the NH group of the triethyl-ammonium cation.

| S-EPMC2967914 | biostudies-literature

1,4-Dibromo-butane-2,3-dione.

Project description:The asymmetric unit of the title compound, C(4)H(4)Br(2)O(2), contains one half-mol-ecule, being located about a centre of inversion. In the crystal, there are no significant inter-molecular inter-actions.

| S-EPMC3515323 | biostudies-literature

(?-Piperazine-1,4-dicarbodithioato-?S,S':S'',S''')bis-[triphenyl-tin(IV)] dichloro-methane solvate.

Project description:The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal-bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol-ecule lies across a centre of inversion. The solvent dichloro-methane mol-ecule is disordered about a centre of inversion.

| S-EPMC2960554 | biostudies-literature

(Ethanol-?O)[2-(4-hydroxy-phen-yl)quinoline-4-carboxyl-ato-?O]triphenyl-tin(IV).

Project description:The Sn atom in the title mol-ecule, [Sn(C(6)H(5))(3)(C(16)H(10)NO(3))(C(2)H(6)O)], shows a trans-C(3)SnO(2) trigonal bipyramidal coord-in-ation. Adjacent mol-ecules are linked by O-H?O and O-H?N hydrogen bonds into a two-dimensional array parallel to (100). The ethanol ligand is disordered, with two sites of equal occupancy being resolved for the ethyl group.

| S-EPMC2977554 | biostudies-literature

[5-(4-Bromo-phenoxy-meth-yl)-1,3,4-thia-diazole-2-thiol-ato]triphenyl-tin(IV).

Project description:In title compound, [Sn(C(6)H(5))(3)(C(9)H(6)BrN(2)OS(2))], the Sn atom is five-coordinated and the 1,3,4-thia-diazole-2-thiol ligand acts as an S,N-bidentate chelating ligand. The five-coordinate Sn(IV) atom forms four primary bonds, three to the phenyl groups and one to the S atom. Thus, the title complex has a distorted cis-trigonal bipyramidal geometry with the S atom and two C atoms occupying the equatorial plane, whereas the N atom and another C atom are in axial positions. In addition, there is a weak intramolecular Sn?N interaction. The crystal structure involves weak intra-molecular C-H?N and inter-molecular C-H?Br hydrogen bonding.

| S-EPMC2977584 | biostudies-literature

μ-Propane-1,3-dithiol-ato-κS,S':S,S'-bis-[dicarbon-yl(triphenyl-phosphane-κP)iron(II)](Fe-Fe).

Project description:The title compound, [Fe(2)(C(3)H(6)S(2))(C(18)H(15)P)(2)(CO)(4)], which might serve as an active-site model of [FeFe]-hydrogenase, contains two fused Fe/S/C/C/C/S six-membered rings, one of which has a chair conformation and the other a boat conformation. Each Fe atom is coordinated by two carbonyl ligands, a triphenyl-phosphane ligand and a bis-bidentate dithiol-ate ligand, and also forms an Fe-Fe bond [2.5167 (16) Å]. Together, the six bonded atoms form a very distorted octa-hedral arrangement.

| S-EPMC3246933 | biostudies-literature

(Dimethyl sulfoxide-?O)di-phenyl-(3-thioxo-3H-1,2-dithiole-4,5-dithiol-ato-?S,S)tin(IV).

Project description:The Sn atom in the title compound, [Sn(C(6)H(5))(2)(C(3)S(5))(C(2)H(6)OS)], exists within a distorted trigonal-bipyramidal geometry defined by two S atoms of the 1,2-dithiole-3-thione-4,5-dithiol-ate dianion, two ipso-C atoms from the phenyl groups, and the O atom of the dimethyl sulfoxide mol-ecule. In this description, one of the S atoms and the O occupy axial positions. In the crystal, centrosymmetrically related mol-ecules associate via pairs of C-H?S contacts, forming dimeric aggregates.

| S-EPMC2971776 | biostudies-literature

[3-(Dimethyl-amino)benzoato]triphenyl-tin(IV).

Project description:In the title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NO(2))], the Sn atom is coordinated by three phenyl groups and a carboxyl-ate anion in a distorted tetra-hedral geometry. An intra-molecular C-H?O inter-action forms an S(7) ring motif. The dihedral angles between the benzoate group and the other three phenyl rings are 76.94?(8), 66.82?(8) and 42.34?(9)°. The crystal structure is further stabilized by inter-molecular C-H?? inter-actions.

| S-EPMC2959792 | biostudies-literature

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