Browse
Submit Data
Databases
API
Help

Dataset Information

19 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(?-Piperazine-1,4-dicarbodithioato-?S,S':S'',S''')bis-[triphenyl-tin(IV)] dichloro-methane solvate.

ABSTRACT: The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal-bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol-ecule lies across a centre of inversion. The solvent dichloro-methane mol-ecule is disordered about a centre of inversion.

SUBMITTER: Poplaukhin P

PROVIDER: S-EPMC2960554 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(μ-Piperazine-1,4-dicarbodithioato-κS,S':S'',S''')bis-[triphenyl-tin(IV)] dichloro-methane solvate.

Poplaukhin Pavel P Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20080816 Pt 9

The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal-bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol-ecule lies across a centre of inversion. The solvent dichloro-methane mol-ecule is disordered about a centre of inversion. ...[more]

PMID: 21201621

Similar Datasets

Bis(triphenyl-phosphine-?P)(tropolonato-?O,O')silver(I) dichloro-methane solvate.

Project description:The title compound, [Ag(C(7)H(5)O(2))(C(18)H(15)P)(2)]·CH(2)Cl(2), crystallizes with a distorted tetra-hedral geometry about the Ag(I) atom, defined by two O atoms from one tropolonate ligand and two P atoms from two triphenyl-phosphine ligands. It is an example of a new type of tropolone derivative that has not been characterized via solid-state methods.

| S-EPMC2968127 | biostudies-literature

(μ-2,3-Dihydroxy-butane-1,4-dithiol-ato)bis-[triphenyl-tin(IV)].

Project description:In the title compound, [Sn(2)(C(6)H(5))(6)(C(4)H(8)O(2)S(2))], the geometry around the Sn atoms is distorted tetra-hedral. The hydr-oxy groups are involved in O-H⋯O hydrogen bonding, which connects mol-ecules into centrosymmetric dimers.

| S-EPMC2979966 | biostudies-literature

trans-(4-Acetyl-naphth-yl)chlorido-bis(triphenyl-phosphine-?P)nickel(II) dichloro-methane solvate.

Project description:The title compound, [Ni(C(12)H(9)O)Cl(C(18)H(15)P)(2)]·CH(2)Cl(2), was synthesized from the reaction between 1-acetyl-4-chloro-naphthalene, NiCl(2)·6H(2)O and triphenyl-phosphine (PPh(3)) in ethanol. The compound contains one crystallographically unique nickel ion in a pseudo-square-planar geometry.

| S-EPMC2959258 | biostudies-literature

?-Oxalato-bis-[bis-(triphenyl-phosphine)copper(I)] dichloro-methane disolvate.

Project description:The dinuclear molecule of the title compound, [Cu(2)(C(2)O(4))(C(18)H(15)P)(4)]·2CH(2)Cl(2), lies across an inversion center with a strictly planar bridging oxalate ligand coordinating two Cu(I) ions via two pairs of O atoms. Two triphenyl-phosphine ligands also coordinate each symmetry-related Cu(I) ion, resulting in a distorted tetra-hedral geometry [O-Cu-O = 80.57?(5)° and P-Cu-P = 125.72?(2)°]. In the crystal, there are two dichloro-methane solvent mol-ecules for each dinuclear complex.

| S-EPMC3569214 | biostudies-literature

?-3-Thienylmalonato-?O:O-bis-[triphenyl-tin(IV)].

Project description:The title compound, [Sn(2)(C(6)H(5))(6)(C(7)H(4)O(4)S)], contains two molecules with similar conformations in the asymmetric unit. In each mol-ecule, the Sn atoms adopt a distorted tetra-hedral geometry arising from three C atoms of three phenyl rings and one O atom from the bridging 3-thienylmalonato ligand. The mol-ecules lie about inversion centers with the ligands facing each other, with C?O distances of 3.417?(10) and 3.475?(10)?Å.

| S-EPMC2959414 | biostudies-literature

2-[Bis(2-amino-ethyl)amino]ethanaminium chloride dichloro-methane solvate.

Project description:In the title compound, C(6)H(19)N(4) (+)·Cl(-)·CH(2)Cl(2), the non-H atoms of the ammonium ion show non-crystallographic C(3) symmetry. The chloride ion is embedded in a framework of seven crystallographically independent hydrogen bonds (five N-H⋯Cl and two C-H⋯Cl), which form layers parallel to the (100) plane. Two N---H...N bonds also occur.

| S-EPMC2960024 | biostudies-literature

[Hydridotris(pyrazol-1-yl-?N(2))borato]bis-(methyl-amino-?N)(triphenyl-phos-phine-?P)ruthenium(II) chloride dichloro-methane solvate monohydrate.

Project description:The title salt, [Ru(Tp)(CH(5)N)(2)(PPh(3))]Cl·CH(2)Cl(2)·H(2)O [where Tp is (C(3)H(3)N(2))(3)BH and PPH(3) is C(18)H(15)P], has the Ru(III) atom in an octa-hedral geometry; one of the Ru-N(Tp) bonds [2.135?(8)?Å] is slightly longer than another two, owing to the trans influence of PPh(3) ligand. N-H?Cl and O-H?Cl hydrogen bonding leads to the formation of layers parallel to (100).

| S-EPMC3515107 | biostudies-literature

?-2-Amino-terephthalato-?O:O-bis-[triphenyl-tin(IV)].

Project description:The title compound, [Sn(2)(C(6)H(5))(6)(C(8)H(5)NO(4))], contains two triphenyl-tin groups bridged by a 2-amino-terephthalate ligand. The two Sn(IV) centers have similar distorted tetra-hedral coordination geometries. Each Sn(IV) atom is bonded to three phenyl C atoms and one O atom from a carboxyl-ate group. The other O atom of the carboxyl-ate group has a weak inter-action with the Sn atom. The amino group is disordered over two sites, with site-occupancy factors of 0.779?(11) and 0.221?(11). Intra-molecular N-H?O hydrogen bonds are observed.

| S-EPMC2971378 | biostudies-other

Butyl-trichlorido{2-[(diisopropyl-ammonio)-meth-yl]phen-yl}tin(IV) dichloro-methane monosolvate.

Project description:The title compound, [Sn(C(4)H(9))(C(13)H(21)N)Cl(3)]·CH(2)Cl(2), was obtained by recrystallization of [2-(diisopropyl-amino-meth-yl)phen-yl]tin(IV) butyl dichloride from a CH(2)Cl(2)/n-hexane mixture (1:4 v/v) in the presence of ambient moisture. Partial hydrolysis led to the title compound, the hydro-chloric acid adduct of the dichloride, having a penta-coordinated Sn atom with a trigonal-bipyramidal C(2)SnCl(3) core. The N atom of the 2-[(diisopropyl-ammonio)-meth-yl]phenyl ligand forms a strong intra-molecular N-H?Cl hydrogen bond, resulting in a zwitterionic species, [2-((i)Pr(2)HN(+)CH(2))C(6)H(4)]SnBuCl(3) (-)·CH(2)Cl(2). Disorder was found in the n-butyl group, which was refined as disordered over three positions, with site occupancies of 0.22?(1), 0.51?(1) and 0.27?(2).

| S-EPMC3050250 | biostudies-literature

[3-(Dimethyl-amino)benzoato]triphenyl-tin(IV).

Project description:In the title compound, [Sn(C(6)H(5))(3)(C(9)H(10)NO(2))], the Sn atom is coordinated by three phenyl groups and a carboxyl-ate anion in a distorted tetra-hedral geometry. An intra-molecular C-H?O inter-action forms an S(7) ring motif. The dihedral angles between the benzoate group and the other three phenyl rings are 76.94?(8), 66.82?(8) and 42.34?(9)°. The crystal structure is further stabilized by inter-molecular C-H?? inter-actions.

| S-EPMC2959792 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data