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(?-Piperazine-1,4-dicarbodithioato-?S,S':S'',S''')bis-[triphenyl-tin(IV)] dichloro-methane solvate.

ABSTRACT: The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal-bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol-ecule lies across a centre of inversion. The solvent dichloro-methane mol-ecule is disordered about a centre of inversion.

SUBMITTER: Poplaukhin P

PROVIDER: S-EPMC2960554 | biostudies-literature | 2008 Aug

REPOSITORIES: biostudies-literature

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(μ-Piperazine-1,4-dicarbodithioato-κS,S':S'',S''')bis-[triphenyl-tin(IV)] dichloro-methane solvate.

Poplaukhin Pavel P Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20080816 Pt 9

The dinuclear centrosymmetric title compound, [Sn(2)(C(6)H(5))(6)(C(6)H(8)N(2)S(4))]·CH(2)Cl(2), features a distorted cis-trigonal-bipyramidal coordination geometry for Sn based on a C(3)S(2) donor set. The dinuclear mol-ecule lies across a centre of inversion. The solvent dichloro-methane mol-ecule is disordered about a centre of inversion. ...[more]

PMID: 21201621

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