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Tris(propane-1,2-diamine-?N,N')nickel(II) tetra-cyanidonickelate(II).

ABSTRACT: The title compound, [Ni(C(3)H(10)N(2))(3)][Ni(CN)(4)], is built up of [Ni(pn)(3)](2+) cations (pn is 1,2-diamino-propane) and [Ni(CN)(4)](2-) anions. Both Ni(II) atoms in the cation and the anion lie on a mirror plane. The respective ions inter-act through Coulombic forces and through a complex network of hydrogen bonds. Extended disorder associated with the cation has been resolved. The occupancies of the respective disordered positions are 0.4:0.4:0.2.

SUBMITTER: Kuchar J

PROVIDER: S-EPMC2960350 | biostudies-literature | 2008 Jan

REPOSITORIES: biostudies-literature

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Tris(propane-1,2-diamine-κN,N')nickel(II) tetra-cyanidonickelate(II).

Kuchár Juraj J Cernák Juraj J

Acta crystallographica. Section E, Structure reports online 20080109 Pt 2

The title compound, [Ni(C(3)H(10)N(2))(3)][Ni(CN)(4)], is built up of [Ni(pn)(3)](2+) cations (pn is 1,2-diamino-propane) and [Ni(CN)(4)](2-) anions. Both Ni(II) atoms in the cation and the anion lie on a mirror plane. The respective ions inter-act through Coulombic forces and through a complex network of hydrogen bonds. Extended disorder associated with the cation has been resolved. The occupancies of the respective disordered positions are 0.4:0.4:0.2. ...[more]

PMID: 21201293

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