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Methyl 2-(5-fluoro-1H-indol-3-yl)-2-oxoacetate.

ABSTRACT: The indolyl portion of the title mol-ecule, C(11)H(8)FNO(3), is flat, the five- and six-membered rings making a dihedral angle of 0.815?(6)°. Inter-molecular N-H?O hydrogen bonds link adjacent mol-ecules into a linear chain. Slipped ?-? stacking inter-actions between two neighboring indole groups further consolidate the mol-ecules into a three-dimensional supra-molecular architecture [centroid-centroid distances = 3.555?(10) and 3.569?(10)?Å].

SUBMITTER: Wang S

PROVIDER: S-EPMC2980012 | biostudies-literature | 2009 Dec

REPOSITORIES: biostudies-literature

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Methyl 2-(5-fluoro-1H-indol-3-yl)-2-oxoacetate.

Wang Shuping S Dong Huajiang H Chen Hong H Zhu Kunpeng K Zhu Tieliang T

Acta crystallographica. Section E, Structure reports online 20091216 Pt 1

The indolyl portion of the title mol-ecule, C(11)H(8)FNO(3), is flat, the five- and six-membered rings making a dihedral angle of 0.815 (6)°. Inter-molecular N-H⋯O hydrogen bonds link adjacent mol-ecules into a linear chain. Slipped π-π stacking inter-actions between two neighboring indole groups further consolidate the mol-ecules into a three-dimensional supra-molecular architecture [centroid-centroid distances = 3.555 (10) and 3.569 (10) Å]. ...[more]

PMID: 21580044

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