Browse
Submit Data
Databases
API
Help

Dataset Information

17 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(Benzyl-diphenyl-phosphane)chlorido-gold(I).

ABSTRACT: In the title compound, [AuCl(C(19)H(17)P)], the Au(I) atom exists within a P and Cl donor set that constitutes an almost linear geometry. The three phenyl rings make dihedral angles of 38.33?(14), 81.26?(15) and 81.28?(14)° with each other. In the crystal, mol-ecules are linked into chains along the b axis by inter-molecular C-H?Cl hydrogen bonds.

SUBMITTER: Shawkataly OB

PROVIDER: S-EPMC3011516 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(Benzyl-diphenyl-phosphane)chlorido-gold(I).

Shawkataly Omar Bin OB Tariq Abu A Yeap Chin Sing CS Fun Hoong-Kun HK

Acta crystallographica. Section E, Structure reports online 20101110 Pt 12

In the title compound, [AuCl(C(19)H(17)P)], the Au(I) atom exists within a P and Cl donor set that constitutes an almost linear geometry. The three phenyl rings make dihedral angles of 38.33 (14), 81.26 (15) and 81.28 (14)° with each other. In the crystal, mol-ecules are linked into chains along the b axis by inter-molecular C-H⋯Cl hydrogen bonds. ...[more]

PMID: 21589233

Similar Datasets

A second polymorph of chlorido(hydroxy-diphenyl-phosphane)gold(I).

Project description:The title complex, [AuCl{(C(6)H(5))(2)P(OH)-?P}] or [AuCl(C(12)H(11)OP)], contains two independent mol-ecules in the asymmetric unit and is a polymorph of a previously reported structure [Hollatz et al. (1999 ?) J. Chem. Soc. Dalton Trans. pp. 111-114]. The crystal structure exhibits inter-molecular Au?Au inter-actions with alternate distances of 3.0112?(3)?Å and 3.0375?(2)?Å. The Cl-Au-P bond angle varies between different mol-ecular units, depending on the degree of influence of the intra-molecular the O-H?Cl hydrogen bond; the angle thus varies between negligible distortion from linearity at 179.23?(3)° and more significant distortion at 170.39?(4)°, which differs from the previously reported polymorph in which both these angles are approximately 170°. The Au-Cl [2.3366?(9) and 2.3131?(10)Å] and Au-P [2.2304?(10) and 2.2254?(10)?Å] bond lengths vary slightly between the two independent mol-ecules but overall, the bond lengths are in good agreement with those in the previously reported polymorph.

| S-EPMC3201275 | biostudies-literature

trans-Bis(benzyl-diphenyl-phosphane-?P)dichloridoplatinum(II).

Project description:In the mononuclear title compound, trans-[PtCl2(C19H17P)2], the slightly distorted square-planar coordination sphere of the Pt(II) atom is occupied by two benzyl-diphenyl-phosphane ligands and two chloride atoms in a mutually trans geometry. The effective cone angles for the two phosphane ligands are 160 and 169°. C-H?Cl inter-actions generate infinite long chains along [01-1]. Additional C-H?? and ?-? stacking interactions [centroid-centroid distance = 4.2499?(15)?Å and ring slippage = 2.386?Å] are observed.

| S-EPMC3588759 | biostudies-literature

Chlorido{[(E)-2-(diphenyl-phosphan-yl)benzyl-idene](furan-2-ylmeth-yl)amine-?P}gold(I).

Project description:In the title complex, [AuCl(C24H20NOP)], the ligand has N, P and O electron-donating atoms but the Au(I) atom is coordinated only by the 'soft' P atom and an additional Cl atom in an almost linear fashion. Important geometrical parameters include Au-P = 2.2321?(13)?Å, Au-Cl = 2.2820?(13)?Å and P-Au-Cl = 176.49?(5)°. The furan ring is disordered over two positions in a 0.51?(2):0.49?(2) ratio.

| S-EPMC3588354 | biostudies-literature

Chlorido{N-[2-(diphenyl-phosphan-yl)benzyl-idene]-2,6-diisopropyl-aniline-?P}gold(I) chloro-form 0.25-solvate.

Project description:The asymmetric unit of the title compound, [AuCl(C31H32NP)]·0.25CHCl3, contains two independent complex mol-ecules and half a chloro-form solvent mol-ecule, which is disordered across an inversion center. The Au(I) ions are each coordinated in a slightly distorted linear environment, with P-Au-Cl angles of 177.20?(4) and 178.54?(4)°.

| S-EPMC3588368 | biostudies-literature

cis-Bis(benzyl-diphenyl-phosphane-?P)dichloridoplatinum(II) dichloro-methane sesquisolvate.

Project description:The asymmetric unit of the title compound, [PtCl(2)(C(19)H(17)P)(2)](2)·3CH(2)Cl(2), contains two complex mol-ecules and three dichloro-methane solvent mol-ecules, two of which are disordered over various positions. The Pt(II) complexes reveal a slightly distorted square-planar geometry with average Pt-P and Pt-Cl bond lengthss of 2.252?(8) and 2.363?(8)?Å, respectively, and average P-Pt-P and Cl-Pt-Cl angles of 99.17?(8) and 87.1?(7)°, respectively.

| S-EPMC3238707 | biostudies-literature

Chlorido[2-(diphenyl-phos-phino)-aceto-phenone]gold(I).

Project description:In the crystal structure of the title compound, [AuCl(C(20)H(17)OP)], the phosphine acts as a monodentate ligand. The Au atoms are attached solely to the P and Cl atoms. The coordination is linear without any tendency to aggregate via aurophilic inter-actions.

| S-EPMC2915127 | biostudies-literature

Chlorido{N-[(E)-2-(diphenyl-phosphan-yl)benzyl-idene]-2-(thio-phen-2-yl)ethan-amine-?P}gold(I).

Project description:The title compound, [AuCl(C(25)H(22)NPS)], crystallizes with two independent mol-ecules in the asymmetric unit in which the thio-phene fragments are disordered over two sets of sites with 0.537?(10):0.463?(10) and 0.701?(9):0.299?(9) occupancy ratios. In both cases, the thio-phene ring is rotated by approximately 180° for the second component. Important geometrical parameters include Au-P = 2.235?(2) and 2.237?(2)?Å, Au-Cl = 2.286?(2) and 2.292?(2)?Å, and P-Au-Cl = 177.39?(8) and 172.63?(7)°. Weak inter-molecular C-H?Cl inter-actions are observed in the crystal structure.

| S-EPMC3254317 | biostudies-literature

Chlorido[1-(diphenyl-phosphan-yl)cobaltocenium]gold(I) hexa-fluoridophosphate.

Project description:In the cobaltocenium group of the title compound, [AuCo(C(5)H(5))(C(17)H(14)P)Cl]PF(6), the substituted cyclo-penta-dienyl (Cps) and the unsubstituted cyclo-penta-dienyl (Cp) ring planes are almost parallel, making a dihedral angle of 3.1?(3)°. The C atoms in Cp and Cps are in an eclipsed conformation. The Au(I) atom is coordinated by a P atom from the diphenyl-phosphanyl group and a Cl atom in an almost linear arrangement [P-Au-Cl = 178.15-(7)°]. Two hexa-fluorido-phosphate anions are each located on a twofold rotation axis. In the crystal, the complex cations and hexa-fluorido-phosphate anions are linked via inter-molecular C-H?F hydrogen bonds.

| S-EPMC3120450 | biostudies-literature

Tricarbonyl-chlorido{N-[2-(diphenyl-phosphino)benzyl-idene]benzyl-amine-?N,P}rhenium(I) dichloro-methane solvate.

Project description:In the crystal structure of the title compound, [ReCl(C(26)H(22)NP)(CO)(3)]·CH(2)Cl(2), the Re(I) atom exhibits a distorted octa-hedral environment defined by a facial arrangement of three carbonyl groups, a Cl atom and an N-[2-(diphenyl-phosphino)benzyl-idene]benzyl-amine ligand. The compound crystallizes with one CH(2)Cl(2) mol-ecule per asymmetric unit. The benzyl-amine ligand and the Re(I) centre form a non-planar six-membered chelate ring.

| S-EPMC2960194 | biostudies-literature

Chlorido(?-1,5-cyclo-octa-diene)[(penta-fluoro-eth-yl)diphenyl-phosphane]iridium(I).

Project description:The title structure,[IrCl(C(8)H(12))(C(14)H(10)F(5)P)], reveals that (C(2)F(5))PPh(2) (penta-fluoro-ethyl-diphenyl-phosphane or pfepp) disrupts the iridium dimer [(cod)IrCl](2) (cod = cyclo-octa-1,5-diene) by rupturing the bridging chloride ligands and binding in the open coordination site to form (cod)Ir(pfepp)Cl with the Ir(I) atom in a distorted square-planar coordination environment. The structure deviates very little from the Ir(I)-triphenyl-phosphine analog, although a significantly (?20?) shorter Ir-P bond is noted for the title compound.

| S-EPMC3050217 | biostudies-other

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data