Unknown

Dataset Information

0

Catena-Poly[[[bis-(1,10-phenanthroline-?N,N')manganese(II)]-?-9,10-dioxo-anthracene-1,5-disulfonato-?O:O] tetra-hydrate].

ABSTRACT: The title complex, {[Mn(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)]·4H(2)O}(n), exhibits a chain-like polymeric structure with 9,10-dioxo-anthracene-1,5-disulfonate anions bridging Mn(II) atoms in a bis-monodentate mode. The unique Mn(II) atom is located on a crystallographic centre of inversion. Four N atoms from two chelating 1,10-phenanthroline ligands and two sulfonate O atoms from two symmetry-related 9,10-dioxoanthracene-1,5-disulfonate anions give rise to a slightly distorted octa-hedral coordination environment around the Mn(II) centre. The centroid of the central ring of the anthraquinone ligand represents another crystallographic centre of inversion. In the crystal structure, inter-ligand ?-? stacking [centroid-to-centroid distances 3.532?(1) and 3.497?(3)?Å] and inter-molecular O-H?O hydrogen-bonding inter-actions assemble the chains into a three-dimensional supra-molecular network.

SUBMITTER: Jia J 

PROVIDER: S-EPMC2969754 | biostudies-literature | 2009 May

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

catena-Poly[[[bis-(1,10-phenanthroline-κN,N')manganese(II)]-μ-9,10-dioxo-anthracene-1,5-disulfonato-κO:O] tetra-hydrate].

Jia Jia J   Feng Wen W   Zhao Hong-Kun HK   Yang En-Cui EC  

Acta crystallographica. Section E, Structure reports online 20090529 Pt 6

The title complex, {[Mn(C(14)H(6)O(8)S(2))(C(12)H(8)N(2))(2)]·4H(2)O}(n), exhibits a chain-like polymeric structure with 9,10-dioxo-anthracene-1,5-disulfonate anions bridging Mn(II) atoms in a bis-monodentate mode. The unique Mn(II) atom is located on a crystallographic centre of inversion. Four N atoms from two chelating 1,10-phenanthroline ligands and two sulfonate O atoms from two symmetry-related 9,10-dioxoanthracene-1,5-disulfonate anions give rise to a slightly distorted octa-hedral coordi  ...[more]

Similar Datasets

Unknown catena-Poly[[bis-(2,2'-bipyridine-?N,N')cadmium(II)]-?-9,10-dioxo-anthracene-1,5-disulfonato-?O:O].
| S-EPMC2971852 | biostudies-other
Unknown Aqua-(9,10-dioxoanthracene-1,5-disul-fonato-κO)bis-(1,10-phenanthroline-κN,N')nickel(II).
| S-EPMC2983167 | biostudies-literature
Unknown Bis(1,10-phenanthrolin-1-ium) 9,10-di-oxo-9,10-dihydroanthracene-1,5-disul-fonate hexa-hydrate.
| S-EPMC3051516 | biostudies-literature
Unknown Aqua-(4,5-dihydroxy-benzene-1,3-disulfonato-κO)bis-(1,10-phenanthroline-κN,N')cadmium(II) monohydrate.
| S-EPMC2960182 | biostudies-literature
Unknown catena-Poly[[(nitrato-κO)(1,10-phenanthroline-κN,N')manganese(II)]-μ-nitrato-κO:O'].
| S-EPMC2914918 | biostudies-literature
Unknown (Formato-κO)bis-(1,10-phenanthroline-κN,N')copper(II) formate hexa-hydrate.
| S-EPMC2960151 | biostudies-literature
Unknown (Heptanedioato-κO,O')bis-(1,10-phenanthroline-κN,N')zinc(II) hexa-hydrate.
| S-EPMC2961045 | biostudies-literature
Unknown 9,10-Dioxo-9,10-di-hydro-anthracene-1,4-diyl di-acetate.
| S-EPMC3648311 | biostudies-literature
Unknown 1,3-Dihydr-oxy-9,10-dioxo-9,10-di-hydro-anthracene-2-carbaldehyde.
| S-EPMC2960756 | biostudies-literature
Unknown N,N'-Diphenyl-9,10-dioxo-9,10-di-hydro-anthracene-2,7-disulfonamide.
| S-EPMC3770431 | biostudies-literature