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[2,6-Bis(6-methyl-quinolin-2-yl)pyridine-?N,N',N'']dichloridomanganese(II).

ABSTRACT: In the mol-ecule of the title compound, [MnCl(2)(C(25)H(19)N(3))], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn(II) atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82?(3):0.18?(3) ratio. Weak inter-molecular C-H?Cl hydrogen bonding occurs in the crystal structure.

SUBMITTER: Li XP

PROVIDER: S-EPMC2983179 | biostudies-literature | 2010 Sep

REPOSITORIES: biostudies-literature

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[2,6-Bis(6-methyl-quinolin-2-yl)pyridine-κN,N',N'']dichloridomanganese(II).

Li Xiao-Ping XP Zhao Jian-She JS Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100925 Pt 10

In the mol-ecule of the title compound, [MnCl(2)(C(25)H(19)N(3))], the three N atoms span the axial-equatorial-axial sites of the trigonal-bipyramidal coordination polyhedron; the geometry of the Mn(II) atom is 34% distorted from trigonal-bipyramidal (towards square-pyramidal along the Berry pseudorotation pathway). One of the Cl atoms is disordered over two positions in a 0.82 (3):0.18 (3) ratio. Weak inter-molecular C-H⋯Cl hydrogen bonding occurs in the crystal structure. ...[more]

PMID: 21587437

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