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Bis[tris-(4-fluoro-phen-yl)phosphine-κP](tropolonato-κO,O')copper(I).

ABSTRACT: The title compound, [Cu(C(7)H(5)O(2))(C(18)H(12)F(3)P)(2)], a copper(I) tris-(4-fluoro-phen-yl)phosphine tropolonate derivative, is the first tropolonate complex with fluorinated aryl-phosphine ligands. The Cu(I) atom has a distorted tetra-hedral coordination; the most important geometrical parameters of the mol-ecule are: Cu-P = 2.2377 (10) and 2.2335 (15) Å, Cu-O = 2.084 (2) and 2.082 (2) Å, O-Cu-O = 77.72 (10)°, P-Cu-P = 128.82 (4)° and O-C-C-O = -2.1 (5)°.

SUBMITTER: Steyl G

PROVIDER: S-EPMC2968941 | biostudies-literature |

REPOSITORIES: biostudies-literature

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trans-Tetra-carbonyl-bis-[tris-(4-fluoro-phen-yl)phosphane-κP]chromium(0).

Project description:In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes that are trans to each other. The Cr atom and two carbonyl groups are on a twofold axis. The benzene rings attached to the phospho-rus atom make dihedral angles of 80.32 (5), 52.91 (5) and 83.80 (5)° with each other. In the crystal, C-H⋯O and C-H⋯F inter-molecular inter-actions form an infinite three-dimensional network.

| S-EPMC3200925 | biostudies-literature

Chlorido[tris-(3-fluoro-phen-yl)phosphine]gold(I).

Project description:In the title gold complex, [AuCl(C(18)H(12)F(3)P)], the P-Au-Cl unit is nearly linear, with an angle of 178.13?(5)°. The three phosphine-substituted benzene rings make dihedral angles of 77.7?(3), 84.4?(3) and 77.4?(3)° with each other. Two of the three F atoms are disordered over two positions, with refined site occupancies of 0.591?(11):0.409?(11) and 0.730?(12):0.270?(12). In the crystal structure, mol-ecules are linked into a three-dimensional network by inter-molecular C-H?Cl and C-H?F hydrogen bonds.

| S-EPMC2983311 | biostudies-literature

(Triphenyl-phosphine-κP)[1,1,1-tris-(diphenyl-phosphinometh-yl)ethane-κP,P',P'']copper(I) tetra-fluoridoborate.

Project description:In the title mononuclear Cu(I) complex, [Cu(C(18)H(15)P)(C(41)H(39)P(3))]BF(4), the cation has a basic rigid core structure reminiscent of the framework of diamond. The metal atom is coordinated by four P atoms in a distorted tetra-hedral geometry, the distortion arising from the steric hindrance of the phenyl groups. The anion is disordered over two positions, with an occupancy ratio of 0.524 (17):0.476 (17). The cations and anions are closely packed in the crystal and are in h.c.p. arrangements.

| S-EPMC2983927 | biostudies-literature

Tris[3,5-bis-(trifluoro-meth-yl)phen-yl]phosphine oxide.

Project description:In the title compound, C(24)H(9)F(18)OP, an intra-molecular C-H?O short contact generates a five-membered ring, producing an S(5) ring motif. The dihedral angles between the benzene rings are 57.68?(10), 77.80?(11) and 79.48?(10)°. Each of the six trifluoro-methyl substituents shows rotational disorder over two positions with refined site-occupany ratios of 0.64?(3)/0.36?(3), 0.649?(14)/0.351?(14), 0.52?(2)/0.48?(2), 0.545?(16)/0.455?(16), 0.774?(9)/0.226?(9) and 0.63?(5)/0.37?(5). The crystal structure is stabilized by inter-molecular C-H?O and C-H?F inter-actions.

| S-EPMC2977759 | biostudies-literature

Chloridotris[tris-(4-fluoro-phen-yl)phosphine]rhodium(I) methanol solvate.

Project description:In the title compound, [RhCl{P(p-FC(6)H(4))(3)}(3)]·CH(3)OH, the Rh atom adopts a distorted square-planar geometry. Rh, Cl and one P atom lie on a mirror plane, as does the solvent molecule. There are two inter-molecular hydrogen bonds, one between the methanol O atom and an aryl H atom (2.51 Å), and one between the Cl atom and the hydr-oxy H atom of methanol [2.34 (3) Å]. The complex precipitates in trace amounts from a reaction between RhCl(cod)(thp) [cod is 1,5-cyclo-octa-diene and thp is tris-(hydroxy-meth-yl)phos-phine] and P(p-FC(6)H(4))(3) under argon in CD(3)OD. Two C(6)H(4)-F units are disordered over two positions; for one the site occupancy factors are ca. 0.53 and 0.47, for the other the values are ca. 0.64 and 0.36. The methyl H atoms of the solvent molecule are disordered across the mirror plane.

| S-EPMC2960913 | biostudies-literature

(Nitrato-?O)tris-[tris-(4-fluoro-phen-yl)phosphane-?P]copper(I).

Project description:In the title complex, [Cu(NO(3))(C(18)H(12)F(3)P)(3)], the ligating atoms define a distorted tetrahedon with the three tris-(4-fluoro-phen-yl)phosphane ligands in the basal positions and the nitrate ligand in the axial position. The intra-molecular ?-? inter-action [centroid-centroid distance = 3.6113?(11)?Å] between two of the 4-fluoro-phenyl groups is complemented by both C-H?F and C-H?O inter-actions with distances in the range 2.51-2.60?Å, resulting in a tight head-to-tail packing.

| S-EPMC3515141 | biostudies-literature

Tris(2-methoxy-phen-yl)phosphine.

Project description:In the title compound, C(21)H(21)O(3)P, the whole mol-ecule is disordered over two sets of positions with refined occupancies of 0.503?(1) and 0.497?(1). The dihedral angles between the three benzene rings are 72.9?(2)°, 82.9?(3)° and 70.0?(2)° in the major disorder component and the corresponding angles in the minor disorder component are 85.0?(2)°, 79.2?(2)° and 72.3?(2)°. The crystal structure is stabilized by C-H?? inter-actions.

| S-EPMC2969262 | biostudies-literature

μ(3)-Iodo-tri-μ(3)-sulfido-sulfidotris[tris-(4-methoxy-phen-yl)phosphine-κP]tri-copper(I)tungsten(VI) N,N-dimethyl-formide solvate.

Project description:A new W/S/Cu cluster, [Cu(3)WIS(4)(C(21)H(21)O(3)P)(3)]·C(3)H(7)NO, was formed by the reaction of ammonium tetra-thio-tungstate(VI), cuprous iodide and tris-(4-methoxy-phen-yl)phosphine in N,N-dimethyl-formamide. The title compound exhibits a heavily distorted cubane-like skeleton in which the average Cu-I, Cu-S and W-μ(3)-S distances are 2.934, 2.302 and 2.249 Å, respectively. The W atom exhibits tetrahedral geometry, formed by three μ(3)-S and one terminal S atom; the W-S(terminal) bond length is 2.1426 (13) Å. Each Cu atom is coordinated by one P atom from a tris-(4-methoxy-phen-yl)phosphine (mop), two μ(3)-S and one μ(3)-I atom, forming a distorted tetra-hedral coordination geometry. Some of the mop ligand methyl groups have large librations. Together with the three neutral mop ligands, the title compound is neutral; this contrasts with the all-halogen-coordinated Mo/S/Ag clusters with the same structure, which carry negative charge.

| S-EPMC2914952 | biostudies-literature

trans-Tetra-carbonyl-bis-[tris-(3-fluoro-phen-yl)phosphane]chromium(0).

Project description:In the title compound, [Cr(C(18)H(12)F(3)P)(2)(CO)(4)], the Cr atom is octa-hedrally coordinated by four carbonyl ligands and the two tertiary phosphanes, which are trans to each other. The three benzene rings in one phosphane ligand make dihedral angles of 53.50?(9), 75.51?(10) and 80.63?(10)° with each other, while in the other ligand these angles are 51.92?(10), 78.56?(11) and 86.80?(10)°. C-H?O and C-H?F inter-actions link the mol-ecules into a three-dimensional network. Each of the F atoms is disordered over two positions with refined occupancies of 0.944?(3):0.056?(3), 0.702?(4):0.298?(4), 0.829?(4):0.171?(4), 0.567?(4):0.433?(4), 0.545?(4):0.455?(4) and 0.920?(4):0.080?(4).

| S-EPMC3238589 | biostudies-literature

(Triphenyl-phosphine-κP)[tris-(indazol-1-yl)borato-κN,N',N'']silver(I).

Project description:The phosphine-coordinated Ag(I) atom in the title compound, [Ag(C(21)H(17)BN(6))(C(18)H(15)P)], is also N,N',N''-chelated by the tris-(indazol-yl)borate anion. The resultant N(3)P coordination geometry is tetra-hedral.

| S-EPMC2915096 | biostudies-literature

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