Browse
Submit Data
Databases
API
Help

Dataset Information

23 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dichloridobis(4-methyl-benz-yl)(1,10-phenanthroline-?N,N')tin(IV).

ABSTRACT: The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octa-hedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methyl-benzyl groups are 21.20?(12) and 28.71?(11)°.

SUBMITTER: Keng TC

PROVIDER: S-EPMC2983632 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dichloridobis(4-methyl-benz-yl)(1,10-phenanthroline-κN,N')tin(IV).

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20100217 Pt 3

The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octa-hedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methyl-benzyl groups are 21.20 (12) and 28.71 (11)°. ...[more]

PMID: 21580246

Similar Datasets

Dichloridobis(2-chloro-benz-yl)tin(IV).

Project description:Mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)], lie on a twofold rotation axis which passes through the Sn atom. The Sn(IV) atom exists in a distorted tetra-hedral geometry. Adjacent mol-ecules are linked by weak Sn?Cl contacts [3.703?(1)?Å], forming a linear chain motif extending along the b axis.

| S-EPMC3007463 | biostudies-literature

Dichloridobis(4-chloro-benzyl-?C)(1,10-phenanthroline-?N,N')tin(IV).

Project description:In the crystal structure of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(12)H(8)N(2))], the Sn(IV) atom is chelated by the N-heterocycle and the metal atom exists in a trans-C(2)SnCl(2)N(2) distorted octa-hedral coordination environment.

| S-EPMC2969476 | biostudies-literature

(2,2'-Bipyridine-?N,N')dichloridobis(4-fluoro-benz-yl)tin(IV).

Project description:The six-coordinate Sn(IV) atom in the title compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(10)H(8)N(2))], shows a trans-C(2)SnN(2)Cl(2) octa-hedral coordination [C-Sn-C = 174.81?(10) and 176.71?(9)° in the two independent mol-ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle.

| S-EPMC3120283 | biostudies-literature

Dichloridobis(4-chloro-benz-yl)(4,4'-dimethyl-2,2'-bipyridine-κN,N')tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(12)H(12)N(2))], is coordinated by the bidentate N-heterocycle mol-ecule, two chloro-benzyl anions and two Cl(-) anions in a distorted trans-C(2)SnCl(2)N(2) octa-hedral geometry [C-Sn-C = 178.4 (1)°]. In the mol-ecular structure, the two benzene rings are oriented at a dihedral angle of 39.62 (17)°.

| S-EPMC2971954 | biostudies-literature

Dimeth-yl(1,10-phenanthroline-?(2) N,N')bis-(thio-cyanato-?N)tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(CH3)2(NCS)2(C12H8N2)], is located on a twofold rotation axis in a distorted octa-hedral enviroment. The methyl groups are trans to each other [C-Sn-C = 175.7?(3)°], whereas the thio-cyanate groups are cis to each other.

| S-EPMC3588785 | biostudies-literature

Trichlorido(4-methyl-benz-yl)bis-(1H-pyrazole-?N)tin(IV).

Project description:The six-coordinate Sn(IV) atom in the title compound, [Sn(C(8)H(9))Cl(3)(C(3)H(4)N(2))(2)], shows an octa-hedral coordination. The N atoms of the N-heterocycle are cis to each other. The Sn-N bond that is trans to the Sn-C bond is shorter than the Sn-N bond trans to the Sn-Cl bond. Weak N-H?Cl hydrogen bonds link adjacent mol-ecules, generating a double chain running along the c axis.

| S-EPMC3120481 | biostudies-literature

Dichloridobis(2-methyl-quinolin-8-olato-?N,O)tin(IV).

Project description:The bis-chelated Sn atom in the title compound, [Sn(C(10)H(8)NO)(2)Cl(2)], exists in a distorted cis-Cl(2),cis-N(2),trans-O(2) octa-hedral environment.

| S-EPMC2969261 | biostudies-literature

Tris(2-chloro-benz-yl)[3-(4-methyl-phen-yl)prop-2-enoato-?O]tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(3)(C(10)H(9)O(2))], exists in a tetra-hedral geometry [? C-Sn-C = 341.5?(4)°]. If the doubly bonded carbonyl O atom is taken into account for the coordination sphere of Sn [Sn?O = 2.808?(2)?Å], the coordination geometry can be described as a cis-penta-gonal bipyramid.

| S-EPMC3120499 | biostudies-literature

Low-temperature redetermination of aqua-chloridotriphenyl-tin(IV)-1,10-phenanthroline (1/1).

Project description:The crystal structure of the title compound, [Sn(C(6)H(5))(3)Cl(H(2)O)]·C(12)H(8)N(2), which was refined in the triclinic space group P [Fu, Gao, Ma & Zhang (2005 ?). Chin. J. Synth. Chem. 13, 55-57], has been redetermined in the monoclinic space group C2/c from low-temperature diffraction measurements. The Sn atom is five-coordinate in a trans-C(3)SnClO trigonal-bipyramidal geometry; the coordinated water mol-ecule forms a pair of hydrogen bonds to the nitro-gen heterocycle.

| S-EPMC2960574 | biostudies-literature

Tetra-chlorido-(1,10-phenanthroline-?N,N')tin(IV) 1,2-dichloro-ethane hemisolvate.

Project description:The asymmetric unit of the title compound, [SnCl(4)(C(12)H(8)N(2))]·0.5C(2)H(4)Cl(2), contains a tin complex and one disordered half-mol-ecule of the solvent dichloro-ethane [occupancies 0.71?(2):0.29?(2)]. The six coordinate Sn(IV) atom adopts a distorted octa-hedral geometry. ?-? inter-actions between adjacent aromatic rings [interplanar distance 3.483?(5)?Å] seem to be effective in the stabilization of the crystal packing.

| S-EPMC2969692 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data