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Dichloridobis(4-methyl-benz-yl)(1,10-phenanthroline-?N,N')tin(IV).


ABSTRACT: The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octa-hedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methyl-benzyl groups are 21.20?(12) and 28.71?(11)°.

SUBMITTER: Keng TC 

PROVIDER: S-EPMC2983632 | biostudies-literature | 2010 Feb

REPOSITORIES: biostudies-literature

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Dichloridobis(4-methyl-benz-yl)(1,10-phenanthroline-κN,N')tin(IV).

Keng Thy Chun TC   Lo Kong Mun KM   Ng Seik Weng SW  

Acta crystallographica. Section E, Structure reports online 20100217 Pt 3


The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octa-hedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methyl-benzyl groups are 21.20 (12) and 28.71 (11)°. ...[more]

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