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Trichlorido(4-methyl-benz-yl)bis-(1H-pyrazole-?N)tin(IV).

ABSTRACT: The six-coordinate Sn(IV) atom in the title compound, [Sn(C(8)H(9))Cl(3)(C(3)H(4)N(2))(2)], shows an octa-hedral coordination. The N atoms of the N-heterocycle are cis to each other. The Sn-N bond that is trans to the Sn-C bond is shorter than the Sn-N bond trans to the Sn-Cl bond. Weak N-H?Cl hydrogen bonds link adjacent mol-ecules, generating a double chain running along the c axis.

SUBMITTER: Keng TC

PROVIDER: S-EPMC3120481 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Trichlorido(4-methyl-benz-yl)bis-(1H-pyrazole-κN)tin(IV).

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The six-coordinate Sn(IV) atom in the title compound, [Sn(C(8)H(9))Cl(3)(C(3)H(4)N(2))(2)], shows an octa-hedral coordination. The N atoms of the N-heterocycle are cis to each other. The Sn-N bond that is trans to the Sn-C bond is shorter than the Sn-N bond trans to the Sn-Cl bond. Weak N-H⋯Cl hydrogen bonds link adjacent mol-ecules, generating a double chain running along the c axis. ...[more]

PMID: 21754571

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