Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

(2,2'-Bipyridine-?N,N')dichloridobis(4-fluoro-benz-yl)tin(IV).

ABSTRACT: The six-coordinate Sn(IV) atom in the title compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(10)H(8)N(2))], shows a trans-C(2)SnN(2)Cl(2) octa-hedral coordination [C-Sn-C = 174.81?(10) and 176.71?(9)° in the two independent mol-ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle.

SUBMITTER: Keng TC

PROVIDER: S-EPMC3120283 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

(2,2'-Bipyridine-κN,N')dichloridobis(4-fluoro-benz-yl)tin(IV).

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110507 Pt 6

The six-coordinate Sn(IV) atom in the title compound, [Sn(C(7)H(6)F)(2)Cl(2)(C(10)H(8)N(2))], shows a trans-C(2)SnN(2)Cl(2) octa-hedral coordination [C-Sn-C = 174.81 (10) and 176.71 (9)° in the two independent mol-ecules in the asymmetric unit]; the Cl atoms are cis to each other as are the N atoms of the chelating N-heterocycle. ...[more]

PMID: 21754570

Similar Datasets

Dichloridobis(4-chloro-benz-yl)(4,4'-dimethyl-2,2'-bipyridine-κN,N')tin(IV).

Project description:The Sn(IV) atom in the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)(C(12)H(12)N(2))], is coordinated by the bidentate N-heterocycle mol-ecule, two chloro-benzyl anions and two Cl(-) anions in a distorted trans-C(2)SnCl(2)N(2) octa-hedral geometry [C-Sn-C = 178.4 (1)°]. In the mol-ecular structure, the two benzene rings are oriented at a dihedral angle of 39.62 (17)°.

| S-EPMC2971954 | biostudies-literature

Dichloridobis(2-chloro-benz-yl)tin(IV).

Project description:Mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)Cl(2)], lie on a twofold rotation axis which passes through the Sn atom. The Sn(IV) atom exists in a distorted tetra-hedral geometry. Adjacent mol-ecules are linked by weak Sn?Cl contacts [3.703?(1)?Å], forming a linear chain motif extending along the b axis.

| S-EPMC3007463 | biostudies-literature

Dichloridobis(4-methyl-benz-yl)(1,10-phenanthroline-?N,N')tin(IV).

Project description:The tin(IV) atom in the title compound, [Sn(C(8)H(9))(2)Cl(2)(C(12)H(8)N(2))], is chelated by the N-heterocycle and bonded to two C atoms and two chloride ions in an SnC(2)Cl(2)N(2) octa-hedral coordination environment with the C atoms trans to each other. The dihedral angles between the heterocycle ring system and the benzene rings of the 4-methyl-benzyl groups are 21.20?(12) and 28.71?(11)°.

| S-EPMC2983632 | biostudies-literature

catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]-?-2-[(piperidin-1-yl)carbothio-ylsulfan-yl]acetato-?O:O'].

Project description:Adjacent units of the title polymeric complex, [Sn(C(7)H(6)F)(3)(C(8)H(12)NO(2)S(2))], are bridged by the carboxyl-ate ion into a helical chain running along the b axis. The Sn(IV) atom shows a distorted trans-C(3)SnO(2) trigonal-bipyramidal coordination and is displaced by 0.113?(2)?Å out of the C(3)Sn girdle in the direction of the covalently bonded O atom. The ring is disordered of two positions with an occupancy of 0.631?(4) for the major occupied site.

| S-EPMC3007486 | biostudies-literature

catena-Poly[[tris-(4-fluoro-benz-yl)tin(IV)]{?-[(N,N-diisopropylcar-bamo-thioyl)sulfanyl]acetato-?O:O'}].

Project description:In the title compound, [Sn(C(7)H(6)F)(3)(C(9)H(16)NO(2)S(2))](n), the Sn atom is coordinated in a slightly distorted, trans-C(3)SnO(2) trigonal-bipyramidal environment. Symmetry-related Sn atoms are bridged by diisopropyl-dithio-carbamoylacetato ligands, forming a one-dimensional polymer along [001].

| S-EPMC2983683 | biostudies-literature

Trichlorido(4-methyl-benz-yl)bis-(1H-pyrazole-?N)tin(IV).

Project description:The six-coordinate Sn(IV) atom in the title compound, [Sn(C(8)H(9))Cl(3)(C(3)H(4)N(2))(2)], shows an octa-hedral coordination. The N atoms of the N-heterocycle are cis to each other. The Sn-N bond that is trans to the Sn-C bond is shorter than the Sn-N bond trans to the Sn-Cl bond. Weak N-H?Cl hydrogen bonds link adjacent mol-ecules, generating a double chain running along the c axis.

| S-EPMC3120481 | biostudies-literature

Bis(4-fluoro-benz-yl-?C)bis-(3-methyl-sulfanyl-1,2,4-thia-diazole-5-thiol-ato-?N,S)tin(IV).

Project description:The mononuclear title molecule, [Sn(C(7)H(6)F)(2)(C(3)H(3)N(2)S(3))(2)], has 2 symmetry. The Sn(IV) atom, located on a twofold rotation axis, is in a skew trapezoidal-bipyramidal geometry, with the basal plane defined by two S,N-chelating 3-methyl-sulfanyl-1,2,4-thia-diazole-5-thiol-ate ligands. The apical positions are occupied by the C atoms of two 4-fluoro-benzyl groups.

| S-EPMC3238646 | biostudies-literature

Aqua-bis-(4-chloro-benz-yl)bis-(nicotinato-?O,O')tin(IV).

Project description:In the title mol-ecule, [Sn(C(7)H(6)Cl)(2)(C(6)H(4)NO(2))(2)(H(2)O)], the O atoms of the two chelating nicotinate groups and the O atom of the coordinated water mol-ecule comprise the penta-gonal plane of the trans-C(2)SnO(5) penta-gonal-bipyramid [C-Sn-C = 178.62?(11) °] surrounding the Sn(IV) atom. In the crystal, adjacent mol-ecules are linked by O-H?N hydrogen bonds, generating a chain running along the body diagonal of the triclinic unit cell.

| S-EPMC3120407 | biostudies-literature

Chloridobis(2-chloro-benz-yl)(quinolin-8-olato-?N,O)tin(IV).

Project description:The Sn(IV) atom in the three independent mol-ecules of the title compound, [Sn(C(7)H(6)Cl)(2)(C(9)H(6)NO)Cl], is N,O-chelated by the quinolin-8-olate anion and exists in a cis-C(2)SnNOCl trigonal-bipyramidal geometry; the O atom of the anion and the two benzyl C atoms lie in the equatorial plane.

| S-EPMC3120540 | biostudies-literature

Tris(2-chloro-benz-yl)(1H-1,2,4-triazole-5-thiol-ato-κS)tin(IV)-tris-(2-chloro-benz-yl)(4H-1,2,4-triazole-3-thiol-ato-κS)tin(IV) (1/1).

Project description:Tris(2-chloro-benz-yl)tin hydroxide condenses with 3-mercapto-1,2,4-triazole to form the 1:1 cocrystal of the title compound, [Sn(C(7)H(6)Cl)(3)(C(2)H(2)N(3)S)]. The asymmetric unit contains two mol-ecules which differ only in the position of the nitro-gen-bound H atom of the triazole ring; one mol-ecule is linked to the other mol-ecule by an N-H⋯N hydrogen bond. In the second mol-ecule, two of the chloro-benzyl units are disordered over two positions in a 0.73 (1):0.27 (1) ratio. The Sn atom in both mol-ecules shows a distorted tetra-hedral SnSC(3) coordination.

| S-EPMC3008140 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data