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[2,2'-Bis(diphenyl-phosphan-yl)-1,1'-binaphthyl-?P,P']chlorido(4-methyl-phenyl-sulfon-yl-?S)palladium(II) dichloro-methane tris-olvate monohydrate.

ABSTRACT: In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P-Pd-P and S-Pd-Cl planes of 28.11?(2)°. The two Pd-P bond lengths differ by about 0.04?Å and the biphosphane bite angle is slightly obtuse [92.92?(2)°]. There are three dichloro-methane and one water mol-ecule co-crystallized with the palladium mol-ecule, all with atoms in general positions. Alternating water and palladium mol-ecules form four-membered cyclic units through O-H?Cl and O-H?O hydrogen bonding. One of the dichloromethane solvent molecules is disordered over two positions in a 0.55:0.45 ratio.

SUBMITTER: Shrestha R 

PROVIDER: S-EPMC3238729 | biostudies-literature | 2011 Dec

REPOSITORIES: biostudies-literature

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[2,2'-Bis(diphenyl-phosphan-yl)-1,1'-binaphthyl-κP,P']chlorido(4-methyl-phenyl-sulfon-yl-κS)palladium(II) dichloro-methane tris-olvate monohydrate.

Shrestha Ruja R   Brennessel William W WW   Weix Daniel J DJ  

Acta crystallographica. Section E, Structure reports online 20111125 Pt 12

In the title compound, [Pd(C(7)H(7)O(2)S)Cl(C(44)H(32)P(2))]·3CH(2)Cl(2)·H(2)O, the geometry around the metal atom is distorted square planar, with a twist angle between the P-Pd-P and S-Pd-Cl planes of 28.11 (2)°. The two Pd-P bond lengths differ by about 0.04 Å and the biphosphane bite angle is slightly obtuse [92.92 (2)°]. There are three dichloro-methane and one water mol-ecule co-crystallized with the palladium mol-ecule, all with atoms in general positions. Alternating water and palladium  ...[more]

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