Unknown

Dataset Information

0

[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

ABSTRACT: Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10?(5) and 177.26?(5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au?O contacts = 3.054?(4) and 3.013?(4)?Å, respectively, for the two mol-ecules].

SUBMITTER: Tadbuppa PP 

PROVIDER: S-EPMC2983779 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

Json Xml
altmetric image

Publications

[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP   Tiekink Edward R T ER  

Acta crystallographica. Section E, Structure reports online 20100327 Pt 4

Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10 (5) and 177.26 (5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au⋯O contacts =  ...[more]

Similar Datasets

Unknown [O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).
| S-EPMC2979177 | biostudies-literature
Unknown [(Z)-O-Isopropyl N-(4-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).
| S-EPMC2983867 | biostudies-other
Unknown [(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).
| S-EPMC2983763 | biostudies-literature
Unknown [(Z)-N-(4-Chloro-phen-yl)-O-methyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).
| S-EPMC2972176 | biostudies-literature
Unknown [(Z)-Ethyl N-isopropyl-thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).
| S-EPMC2979388 | biostudies-literature
Unknown [(Z)-N,O-Disopropyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).
| S-EPMC2971935 | biostudies-literature
Unknown [(Z)-N-(2-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).
| S-EPMC2971960 | biostudies-literature
Unknown [(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).
| S-EPMC2979546 | biostudies-other
Unknown [(Z)-N-(2-Chloro-phen-yl)-O-methyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).
| S-EPMC2971876 | biostudies-other
Unknown [(Z)-O-Ethyl N-(4-chloro-phen-yl)thio-carbamato-?S](triphenyl-phosphine-?P)gold(I) dichloro-methane hemisolvate.
| S-EPMC2979641 | biostudies-literature