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[O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

ABSTRACT: The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62?(5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970?(5)?Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2979177 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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[O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100410 Pt 5

The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group. ...[more]

PMID: 21578999

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[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10?(5) and 177.26?(5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au?O contacts = 3.054?(4) and 3.013?(4)?Å, respectively, for the two mol-ecules].

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Project description:The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44?(5)°], with the distortion due in part to a close intra-molecular Au?O contact [3.023?(4)?Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618?(15):0.382?(15) ratio.

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[(Z)-O-Isopropyl N-(4-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au atom in the title compound, [Au(C(10)H(11)ClNOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 172.45?(5)°], with the distortion due in part to a close intra-molecular Au?O contact [3.134?(3)?Å].

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Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], features a linear S,P-donor set with a small deviation from the ideal linear geometry due to the proximity of the meth-oxy O atom to Au [Au⋯O = 2.986 (4) Å].

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[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73?(3)°], with the distortion due in part to a close intra-molecular Au?O contact [3.060?(3)?Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H??.

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Project description:In the title compound, [Au(C(7)H(14)NOS)(C(18)H(33)P)], the Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.94 (2)°], with the distortion due to a short intra-molecular Au⋯O contact [2.908 (2) Å].

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Project description:The Au(I) atom in the title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)]·0.5CH(2)Cl(2), exists within a slightly distorted linear geometry defined by an S,P donor set [S-Au-P angle = 178.01?(4)°]; a close intra-molecular Au?O contact [2.964?(4)?Å] also occurs. In the crystal structure, mol-ecules are linked into supra-molecular chains propagating along [010] by C-H?N, C-H?S and C-H?? inter-actions. The solvent mol-ecule is disordered about a twofold rotation axis.

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[(Z)-N-(4-Chloro-phen-yl)-O-methyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(8)H(7)ClNOS)(C(18)H(15)P)], is characterized by a linear S,P-donor set with a small deviation from the ideal linearity [S-Au-P = 175.14?(5)°] due to the close approach of the O atom to the Au atom [Au?O = 2.882?(3)?Å]. Loosely associated dimers are formed in the crystal structure through C-H?O inter-actions.

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[(Z)-O-Ethyl N-phenyl-thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I): a monoclinic polymorph.

Project description:The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P) polymorph [Hall et al. (1993 ?). Aust. J. Chem.46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43?(3)°], with the distortion due in part to a close intra-molecular Au?O contact [3.036?(2)?Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H?? inter-actions.

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[(Z)-N-(3-Chloro-phen-yl)-O-ethyl-thio-carbamato-?S](triphenyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], reveals a near linear geometry for the Au atom defined by a S,P-donor set [S-Au-P = 175.86?(3)°]. The deviation from linearity is ascribed to the proximate O atom derived from the thio-carbamato anion [Au?O = 2.967?(3)?Å].

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