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[O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

ABSTRACT: The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62?(5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970?(5)?Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group.

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2979177 | biostudies-literature | 2010 Apr

REPOSITORIES: biostudies-literature

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[O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Tadbuppa Primjira P PP Tiekink Edward R T ER

Acta crystallographica. Section E, Structure reports online 20100410 Pt 5

The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62 (5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970 (5) Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group. ...[more]

PMID: 21578999

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