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[(Z)-N,O-Disopropyl-thio-carbamato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

ABSTRACT: In the title compound, [Au(C(7)H(14)NOS)(C(18)H(33)P)], the Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.94 (2)°], with the distortion due to a short intra-molecular Au⋯O contact [2.908 (2) Å].

SUBMITTER: Tadbuppa PP

PROVIDER: S-EPMC2971935 | biostudies-literature |

REPOSITORIES: biostudies-literature

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[(Z)-O-Isopropyl N-phenyl-thio-car-bam-ato-κS](tricyclo-hexyl-phosphine-κP)gold(I).

Project description:The Au atom in the title compound, [Au(C(10)H(12)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.54 (2)°], with the distortion due in part to a close intra-molecular Au⋯O contact [3.1702 (16) Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H⋯O inter-actions.

| S-EPMC2983967 | biostudies-literature

[(Z)-Ethyl N-isopropyl-thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au(I) atom in the title compound, [Au(C(6)H(12)NOS)(C(18)H(33)P)], is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P angle = 173.44?(5)°], with the distortion due in part to a close intra-molecular Au?O contact [3.023?(4)?Å]. The N-bound isopropyl group is disordered over two orientations in a 0.618?(15):0.382?(15) ratio.

| S-EPMC2979388 | biostudies-literature

[(Z)-O-Ethyl-N-(o-tol-yl)thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(10)H(12)NOS)(C(18)H(15)P)], features a linear geometry for the Au atom defined by the S and P donor atoms. A small deviation from the ideal geometry is noted and is ascribed to an intra-molecular Au⋯O contact [2.936 (4) Å]. Inversion dimers are formed in the crystal structure mediated by C-H⋯π inter-actions between centrosymmetrically related o-tolyl residues [C⋯Cg = 3.532 (6) Å].

| S-EPMC2971922 | biostudies-literature

[(Z)-N-(2-Chloro-phen-yl)-O-ethyl-thio-carbamato-κS](triphenyl-phosphine-κP)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(15)P)], features a linear S,P-donor set with a small deviation from the ideal linear geometry due to the proximity of the meth-oxy O atom to Au [Au⋯O = 2.986 (4) Å].

| S-EPMC2971960 | biostudies-literature

[(Z)-O-Isopropyl N-(m-tol-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au atom in the title compound, [Au(C(11)H(14)NOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 174.73?(3)°], with the distortion due in part to a close intra-molecular Au?O contact [3.060?(3)?Å]. In the crystal structure, mol-ecules are arranged in layers in the bc plane with the primary connections between the arrays being of the type C-H??.

| S-EPMC2983763 | biostudies-literature

[O-Ethyl (Z)-N-(2-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The title compound, [Au(C(9)H(9)ClNOS)(C(18)H(33)P)], features a slightly distorted linear coordination geometry for the Au atom defined by a S,P-donor set [S-Au-P = 177.62?(5)°]. The distortion is ascribed to the close approach of the O atom, which forms an intra-molecular contact of 2.970?(5)?Å. Disorder was found in the structure with two positions of equal weight being resolved for the C atoms comprising the eth-oxy group.

| S-EPMC2979177 | biostudies-literature

[(Z)-O-Methyl N-(3-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:Two independent mol-ecules comprise the asymmetric unit of the title compound, [Au(C(8)H(7)ClNOS)(C(18)H(33)P)], which differ in the relative orientations of each of the cyclo-hexyl groups as well as the benzene ring. In each mol-ecule, the Au atom is coordinated within a S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 175.10?(5) and 177.26?(5)° for the two mol-ecules], with the distortion due in part to the close intra-molecular approach of the O atom [Au?O contacts = 3.054?(4) and 3.013?(4)?Å, respectively, for the two mol-ecules].

| S-EPMC2983779 | biostudies-literature

[(Z)-O-Ethyl N-phenyl-thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I): a monoclinic polymorph.

Project description:The title compound, [Au(C(9)H(10)NOS)(C(18)H(33)P)], represents a monoclinic polymorph to complement a previously reported triclinic (P) polymorph [Hall et al. (1993 ?). Aust. J. Chem.46, 561-570 (unit-cell data only)]. The Au(I) atom is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = = 175.43?(3)°], with the distortion due in part to a close intra-molecular Au?O contact [3.036?(2)?Å]. In the crystal structure, mol-ecules are arranged into supra-molecular chains along the b axis mediated by C-H?? inter-actions.

| S-EPMC2983808 | biostudies-other

[(Z)-O-Isopropyl N-(4-chloro-phen-yl)thio-carbamato-?S](tricyclo-hexyl-phosphine-?P)gold(I).

Project description:The Au atom in the title compound, [Au(C(10)H(11)ClNOS)(C(18)H(33)P)], is coordinated within an S,P-donor set that defines a slightly distorted linear geometry [S-Au-P = 172.45?(5)°], with the distortion due in part to a close intra-molecular Au?O contact [3.134?(3)?Å].

| S-EPMC2983867 | biostudies-other

Tricarbonyl-bis(tricyclo-hexyl-phosphine-κP)ruthenium(0) toluene solvate.

Project description:The title compound, [Ru(C(18)H(33)P)(2)(CO)(3)]·C(7)H(8), shows a distorted trigonal-bipyramdial coordination around the central Ru atom, with the two phosphine ligands occupying the axial positions. Two toluene mol-ecules per asymmetric unit with site-occupation factors of 0.5 are observed. One of them forces two of the CO ligands to enclose a wider C-Ru-C bond angle [127.5 (3)°] than in the solvent-free crystal structure of [Ru(PCy(3))(2)(CO)(3)] (Cy is cyclo-hexyl).

| S-EPMC2959764 | biostudies-literature

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