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Bis[N-(1-naphth-yl)ethyl-enediammonium] hexa-bromidoplumbate(II).

ABSTRACT: The title compound, (C(12)H(16)N(2))(2)[PbBr(6)], is an organic-inorganic salt, with two doubly protonated N-(1-naphth-yl)ethyl-enediammonium cations and one octa-hedral hexa-bromidoplumbate(II) anion. The Pb(II) atom is located on a centre of inversion. The crystal structure consists of alternating inorganic and organic layers parallel to the bc plane. Face-to-face aromatic stacking inter-actions [centroid-centroid distance = 3.505 (5) Å] occur between parallel naphthalene systems in the organic layers, and N-H⋯Br hydrogen bonds between the cations and anions stabilize the crystal structure.

SUBMITTER: Chen Y

PROVIDER: S-EPMC2983965 | biostudies-literature |

REPOSITORIES: biostudies-literature

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Bis(ethyl-enediammonium) tetra-deca-borate.

Project description:The title compound, 2C(2)H(10)N(2) (2+)·B(14)O(20)(OH)(6) (4-), consists of a centrosymmetric tetra-deca-borate anion and two ethyl-enediammonium cations. The anions are inter-connected through strong O-H⋯O hydrogen bonds into a three-dimensional supra-molecular network with channels along [100], [010], [001] and [111]. The diprotonated cations reside in the channels and inter-act with the inorganic framework by extensive N-H⋯O hydrogen bonds.

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| S-EPMC2971149 | biostudies-literature

Ethyl-enediammonium bis-(3,4-dihy-droxy-benzoate) monohydrate.

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| S-EPMC3009286 | biostudies-literature

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Project description:In the structure of the title compound, [Pd(C(19)H(21)N(2)P)(2)](PF(6))(2)·2.85CH(3)CN, the two six-membered NHC-phosphane chelate rings form a distorted square-planar coordination geometry around the Pd(II) atom, which lies 0.212?(1)?Å above the coordination plane. The sum of the bond angles at Pd(II) is 358.3°, with C-Pd-P bite angles of 84.03?(10) and 83.54?(9)°. The structure includes three acetonitrile solvent mol-ecules, one with partial site occupation and one with severe disorder, which was eventually excluded from the refinement.

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Bis(2,2'-bipyridine){ethyl 4'-[N-(4-carbamoylphen-yl)carbamo-yl]-2,2'-bi-pyridine-4-carboxyl-ate}ruthenium(II) bis-[hexa-fluorido-phosphate(V)].

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| S-EPMC2968400 | biostudies-literature

Crystal structure of bis-(1-ethyl-pyridinium) dioxonium hexa-cyanidoferrate(II).

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| S-EPMC5290569 | biostudies-literature

Bis[?-3,5-bis-(pyridin-2-yl)pyrazolato]bis-[(hexa-fluoro-phosphato)copper(II)].

Project description:The title dinuclear complex mol-ecule, [Cu2(C13H9N4)2(PF6)2], lies about an inversion center. The Cu(II) atom shows a square-pyramidal coordination geometry with the basal plane formed by four N atoms of the two bis-chelating 3,5-bis-(pyridin-2-yl)pyrazolate ions and with one F atom of the hexa-fluoro-phosphate ion in the apical position. Mol-ecules are stacked in a column along the a axis through C-H?F hydrogen bonds. The columns are further linked by other C-H?F hydrogen bonds, forming a three-dimensional network.

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Ethyl-enediammonium dichloride.

Project description:The title ionic compound, C(2)H(10)N(2) (2+)·2Cl(-), crystallizes with a center of symmetry within the cation. Each of the positively charged ammonium ends of the mol-ecule is trigonally hydrogen bonded to three different chloride counter-ions, while each of the chloride ions is trigonally hydrogen bonded to three different ethyl-enediammonium cations. The hydrogen-bonding network leads to stabilization of the structure.

| S-EPMC2969764 | biostudies-literature

A second monoclinic polymorph of ethyl-enediammonium bis-(hydrogen squarate) monohydrate.

Project description:The title compound, C(2)H(10)N(2) (2+)·2HC(4)O(4) (-)·H(2)O, a new polymorph of ethyl-enediammonium bis-(hydrogen squarate) monohydrate, was synthesized by slow evaporation of an acid solution. The asymetric unit contains two hydrogen squarate anions, two half-mol-ecules of protonated ethyl-enediamine arranged around a twofold axis and one water mol-ecule. In the crystal, N-H?O and O-H?O hydrogen bonds between the hydrogen squarate anions, protonated N atoms from the amine group and water mol-ecules lead to a three-dimensional framework. In particular, the cohesion between the squarate groups is ensured by very short intermolecular hydrogen bonds bonds. The title compound crystallized together with the previously reported polymorph [Mathew et al. (2002 ?). J. Mol. Struct.641, 263-279].

| S-EPMC3089163 | biostudies-literature

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