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Ethyl-enediammonium tetraaquadi-sulfatomagnesium(II).

ABSTRACT: The title compound, [NH(3)(CH(2))(2)NH(3)][Mg(SO(4))(2)(H(2)O)(4)], was synthesized by the slow evaporation method. Its crystal structure can be described as an alternate stacking of inorganic layers of tetra-aqua-bis(sulfato-O)magnesium [Mg(SO(4))(2)(H(2)O)(4)](2-) anions ( symmetry) and organic layers of [NH(3)(CH(2))(2)NH(3)](2+) cations along the crystallographic b axis. The anions, built up from tetrahedral SO(4) units and octahedral Mg(H(2)O)(4)O(2) units, and the cations are linked together through N-H?O hydrogen bonds, forming a three-dimensional network. O-H?O inter-actions are also present.

SUBMITTER: Rekik W

PROVIDER: S-EPMC2971149 | biostudies-literature | 2009 Oct

REPOSITORIES: biostudies-literature

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Ethyl-enediammonium tetraaquadi-sulfatomagnesium(II).

Rekik Walid W Naïli Houcine H Mhiri Tahar T Bataille Thierry T

Acta crystallographica. Section E, Structure reports online 20091023 Pt 11

The title compound, [NH(3)(CH(2))(2)NH(3)][Mg(SO(4))(2)(H(2)O)(4)], was synthesized by the slow evaporation method. Its crystal structure can be described as an alternate stacking of inorganic layers of tetra-aqua-bis(sulfato-O)magnesium [Mg(SO(4))(2)(H(2)O)(4)](2-) anions ( symmetry) and organic layers of [NH(3)(CH(2))(2)NH(3)](2+) cations along the crystallographic b axis. The anions, built up from tetrahedral SO(4) units and octahedral Mg(H(2)O)(4)O(2) units, and the cations are linked togeth ...[more]

PMID: 21578145

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