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Diacetatobis(propane-1,3-diamine)nickel(II) dihydrate.


ABSTRACT: In the title complex, [Ni(CH(3)COO)(2)(C(3)H(10)N(2))(2)]·2H(2)O, the Ni(II) atom resides on a centre of symmetry and is in an octa-hedral coordination environment comprising four amino N atoms and two carboxyl-ate O atoms. Inter-molecular N-H?O and O-H?O hydrogen bonds produce R(2) (1)(6), R(2) (2)(12), R(3) (2)(8) and R(5) (5)(16) rings, which generate a two-dimensional polymeric network parallel to (001).

SUBMITTER: Khan IU 

PROVIDER: S-EPMC2984075 | biostudies-literature | 2010 Mar

REPOSITORIES: biostudies-literature

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Diacetatobis(propane-1,3-diamine)nickel(II) dihydrate.

Khan Islam Ullah IU   Ejaz   Sahin Onur O   Büyükgüngör Orhan O  

Acta crystallographica. Section E, Structure reports online 20100324 Pt 4


In the title complex, [Ni(CH(3)COO)(2)(C(3)H(10)N(2))(2)]·2H(2)O, the Ni(II) atom resides on a centre of symmetry and is in an octa-hedral coordination environment comprising four amino N atoms and two carboxyl-ate O atoms. Inter-molecular N-H⋯O and O-H⋯O hydrogen bonds produce R(2) (1)(6), R(2) (2)(12), R(3) (2)(8) and R(5) (5)(16) rings, which generate a two-dimensional polymeric network parallel to (001). ...[more]

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