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Dichloridobis(4-fluoro-aniline-?N)zinc.

ABSTRACT: In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra-hedral geometry, being coordinated by the N atoms of two 4-fluoro-aniline mol-ecules and the two Cl(-) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96?(13)°. In the crystal, mol-ecules are linked via pairs of N-H?Cl hydrogen bonds, forming chains propagating along the b axis. These chains are in turn linked via a second pair of N-H?Cl hydrogen bonds, forming a two-dimensional network parallel to the ab plane. The title compound crystallizes in the space group Pca2(1) and exhibits weak second harmonic generation (SHG) properties.

SUBMITTER: Subashini A

PROVIDER: S-EPMC3435581 | biostudies-literature | 2012 Sep

REPOSITORIES: biostudies-literature

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Dichloridobis(4-fluoro-aniline-κN)zinc.

Subashini Ashokkumar A Ramamurthi Kandasamy K Stoeckli-Evans Helen H

Acta crystallographica. Section E, Structure reports online 20120804 Pt 9

In the title compound, [ZnCl(2)(C(6)H(6)FN)(2)], the Zn(II) atom has a slightly distorted tetra-hedral geometry, being coordinated by the N atoms of two 4-fluoro-aniline mol-ecules and the two Cl(-) anions. The two benzene rings are almost perpendicular to one another, making a dihedral angle of 89.96 (13)°. In the crystal, mol-ecules are linked via pairs of N-H⋯Cl hydrogen bonds, forming chains propagating along the b axis. These chains are in turn linked via a second pair of N-H⋯Cl hydrogen bo ...[more]

PMID: 22969454

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