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Bis(dimethyl sulfoxide)-hydridobis(triphenyl-phosphane)cobalt(I).

ABSTRACT: The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl-phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol-yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axial positions.

SUBMITTER: Hapke M

PROVIDER: S-EPMC3007366 | biostudies-literature | 2010

REPOSITORIES: biostudies-literature

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Bis(dimethyl sulfoxide)-hydridobis(triphenyl-phosphane)cobalt(I).

Hapke Marko M Weding Nico N Spannenberg Anke A

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8

The title compound, [CoH(C(18)H(15)P)(2)(C(2)H(6)OS)(2)], was synthesized by the reaction of chloridotris(triphenyl-phosphane)cobalt(I), [ClCo(PPh(3))(3)], in the presence of one equivalent potassium hydridotris(pyrazol-yl)borate in dimethyl sulfoxide. The structure displays a distorted trigonal-pyramidally coordinated cobalt(I) atom, with two phosphane ligands and one DMSO ligand in the equatorial plane. The coordination is completed by one further DMSO ligand and the anionic hydride in the axi ...[more]

PMID: 21588105

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