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Chlorido(1H-imidazole-?N)bis-(triphenyl-phosphane-?P)copper(I).

ABSTRACT: In the title complex, [CuCl(C(3)H(4)N(2))(C(18)H(15)P)(2)], the coordination geometry around Cu(I) is distorted tetra-hedral formed by two triphenyl-phosphane ligands, an imidazole ligand and a chloride group. An intra-molecular C-H?Cl inter-action occurs. The crystal packing is stabilized by inter-molecular N-H?Cl hydrogen bonds, which form an extended chain parallel to [010].

SUBMITTER: Hossaini Sadr M

PROVIDER: S-EPMC3120300 | biostudies-literature | 2011 Jun

REPOSITORIES: biostudies-literature

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Chlorido(1H-imidazole-κN)bis-(triphenyl-phosphane-κP)copper(I).

Hossaini Sadr Moayad M Kia Reza R Soltani Behzad B

Acta crystallographica. Section E, Structure reports online 20110520 Pt 6

In the title complex, [CuCl(C(3)H(4)N(2))(C(18)H(15)P)(2)], the coordination geometry around Cu(I) is distorted tetra-hedral formed by two triphenyl-phosphane ligands, an imidazole ligand and a chloride group. An intra-molecular C-H⋯Cl inter-action occurs. The crystal packing is stabilized by inter-molecular N-H⋯Cl hydrogen bonds, which form an extended chain parallel to [010]. ...[more]

PMID: 21754651

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