Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dibromido{2-[1-(cyclo-propyl-imino)-eth-yl]pyridine}-zinc(II).

ABSTRACT: In the title compound, [ZnBr(2)(C(10)H(12)N(2))], the Zn(2+) ion is coordinated by the N,N'-bidentate Schiff base ligand and two bromode ions in a distorted tetra-hedral arrangement. The dihedral angle between the pyridine and the cyclo-propyl rings is 95.4?(8)°.

SUBMITTER: Yue SY

PROVIDER: S-EPMC3007484 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dibromido{2-[1-(cyclo-propyl-imino)-eth-yl]pyridine}-zinc(II).

Yue Si-Yu SY Lu Jiu-Fu JF

Acta crystallographica. Section E, Structure reports online 20100703 Pt 8

In the title compound, [ZnBr(2)(C(10)H(12)N(2))], the Zn(2+) ion is coordinated by the N,N'-bidentate Schiff base ligand and two bromode ions in a distorted tetra-hedral arrangement. The dihedral angle between the pyridine and the cyclo-propyl rings is 95.4 (8)°. ...[more]

PMID: 21588127

Similar Datasets

Dibromido{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-?N,N'}zinc(II).

Project description:In the title complex, [ZnBr(2)(C(12)H(9)BrN(2))], the Zn(II) ion is in a distorted tetra-hedral coordination environment formed by two imine N atoms of the bis-chelating N-heterocyclic ligand and two Br atoms. The dihedral angle between the pyridine and benzene rings is 8.04?(17)°.

| S-EPMC2977329 | biostudies-literature

Dibromido{2-[(4-nitro-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).

Project description:In the title compound, [ZnBr(2)(C(12)H(9)N(3)O(2))], the Zn(II) ion is bonded to two Br ions and two N atoms of the diimine ligand in a distorted tetra-hedral geometry. With the exception of the Br atoms, all other atoms are disordered over two sets of sites corresponding to a 180° rotation of the mol-ecule along [[Formula: see text]02]. The refined occupancies of the components are 0.809 (2) and 0.191 (2). In addition, the crystal studied was a non-merohedral twin with a refined component ratio of 0.343 (2):0.657 (2).

| S-EPMC3246977 | biostudies-literature

Bis[2-(cyclo-propyl-imino-meth-yl)-5-methoxy-phenolato]zinc(II).

Project description:In the title complex, [Zn(C(11)H(12)NO(2))(2)], the Zn(2+) ion (site symmetry 2) is coordinated by two N,O-bidentate Schiff base ligands, generating a tetra-hedral ZnO(2)N(2) geometry for the metal ion.

| S-EPMC2979218 | biostudies-literature

Dibromido{(E)-2-eth-oxy-6-[3-(methyl-ammonio)propyl-iminometh-yl]phenol-ato}zinc(II).

Project description:The title complex, [ZnBr(2)(C(13)H(20)N(2)O(2))], is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base (E)-2-eth-oxy-6-((3-(methyl-amino)propyl-imino)meth-yl)phenol. The Zn(II) atom is four-coordinated by the imine N and phenolate O atoms of the Schiff base ligand, and by two bromide ions, in a tetra-hedral coordination geometry. Adjacent mol-ecules are linked through inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.

| S-EPMC2961999 | biostudies-literature

Dibromido{2-[(4-fluoro-phen-yl)imino-meth-yl]pyridine-?(2)N,N'}zinc.

Project description:In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49?(1)°. In the crystal, weak C-H?F and C-H?Br hydrogen bonds are observed.

| S-EPMC3414158 | biostudies-literature

Dibromido{2-[2-(piperidinium-1-yl)ethyl-imino-meth-yl]phenolato}zinc(II) monohydrate.

Project description:The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol-ecule and a solvent water mol-ecule. The Zn(II) atom is four-coordinated in an approximately tetra-hedral geometry, binding to the imine N and phenolate O atoms of the neutral zwitterionic Schiff base ligand and to two terminal Br(-) anions. In the crystal structure, mol-ecules are linked through inter-molecular O-H?Br and O-H?O hydrogen bonds, forming chains running along the b axis.

| S-EPMC2961651 | biostudies-literature

{2,6-Bis[1-(phenyl-imino)eth-yl]pyridine-?N,N',N''}dichloridocobalt(II).

Project description:In the title complex, [CoCl(2)(C(21)H(19)N(3))], the Co(II) atom is coordinated by one pyridine and two imine N atoms and by two chloride anions in a distorted trigonal bipyramidal geometry. The structure exhibits a pseudo-mirror plane through the metal atom, two chloride anions and the pyridine ring. In the crystal structure, the complexes are connected via inter-molecular C-H?Cl hydrogen bonding.

| S-EPMC2961630 | biostudies-literature

Dichlorido{2-[3-(dimethyl-ammonio)-propyl-imino-meth-yl]phenolato}zinc(II) hemihydrate.

Project description:The title complex, [ZnCl(2)(C(12)H(18)N(2)O)]·0.5H(2)O, is a mononuclear zinc(II) compound derived from the zwitterionic form of the Schiff base 2-[3-(dimethyl-amino)propyl-imino-meth-yl]-phenol. The Zn(II) atom is four-coordinated by the imine N and the phenolate O atoms of the Schiff base ligand, and by two chloride ions, in a distorted tetra-hedral coordination geometry. The dimethyl-ammonio group is disordered over two positions with site occupancies of 0.51 (3) and 0.49 (3). In the asymmetric unit, there is also a disordered water mol-ecule with a partial occupancy of 0.5. In the crystal structure, the water mol-ecules are linked to the Schiff base complex mol-ecules through inter-molecular N-H⋯O hydrogen bonds. Mol-ecules are further linked through additional inter-molecular N-H⋯O hydrogen bonds, forming chains running along the b axis.

| S-EPMC2959570 | biostudies-literature

cis-Bis[2-(cyclo-propyl-imino-meth-yl)-6-methoxy-phenolato]bis-(thio-cyanato)cobalt(II).

Project description:In the title compound, [Co(NCS)(2)(C(11)H(13)NO(2))(2)], a mononuclear Schiff base cobalt(II) complex, the Co atom is six-coordinated by four O atoms from two Schiff base ligands, and by two N atoms from two thio-cyanate ligands, forming a distorted octa-hedral geometry. The central Co atom lies on a twofold rotation axis. An intramolecular N-H⋯O hydrogen bond is present.

| S-EPMC2914956 | biostudies-literature

2,6-Bis[1-(2-methyl-phenyl-imino)eth-yl]pyridine.

Project description:The mol-ecule of the title compound, C(23)H(23)N(3), which was synthesized by the condensation reaction between 2,6-diacetyl-pyridine and 2-dimethyl-aniline, adopts an E configuration about both C=N imine bonds. The dihedral angles formed by the benzene rings with the pyridine ring are 89.68?(5) and 53.62?(6)°.

| S-EPMC2969280 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data