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Dibromido{2-[(4-fluoro-phen-yl)imino-meth-yl]pyridine-?(2)N,N'}zinc.

ABSTRACT: In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49?(1)°. In the crystal, weak C-H?F and C-H?Br hydrogen bonds are observed.

SUBMITTER: Dehghanpour S

PROVIDER: S-EPMC3414158 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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Dibromido{2-[(4-fluoro-phen-yl)imino-meth-yl]pyridine-κ(2)N,N'}zinc.

Dehghanpour Saeed S Mahmoudi Ali A

Acta crystallographica. Section E, Structure reports online 20120725 Pt 8

In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49 (1)°. In the crystal, weak C-H⋯F and C-H⋯Br hydrogen bonds are observed. ...[more]

PMID: 22904765

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