Browse
Submit Data
Databases
API
Help

Dataset Information

0 Views

0 Connections

0 Citations

0 Reanalyses

0 Downloads

Omics score: 0

Dibromido{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-?N,N'}zinc(II).

ABSTRACT: In the title complex, [ZnBr(2)(C(12)H(9)BrN(2))], the Zn(II) ion is in a distorted tetra-hedral coordination environment formed by two imine N atoms of the bis-chelating N-heterocyclic ligand and two Br atoms. The dihedral angle between the pyridine and benzene rings is 8.04?(17)°.

SUBMITTER: Khalaj M

PROVIDER: S-EPMC2977329 | biostudies-literature | 2009 Jul

REPOSITORIES: biostudies-literature

ACCESS DATA

Json Xml

Publications

Dibromido{2-[(4-bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).

Khalaj Mehdi M Dehghanpour Saeed S Mahmoudi Ali A Seyedidarzam Shila S

Acta crystallographica. Section E, Structure reports online 20090711 Pt 8

In the title complex, [ZnBr(2)(C(12)H(9)BrN(2))], the Zn(II) ion is in a distorted tetra-hedral coordination environment formed by two imine N atoms of the bis-chelating N-heterocyclic ligand and two Br atoms. The dihedral angle between the pyridine and benzene rings is 8.04 (17)°. ...[more]

PMID: 21583353

Similar Datasets

Dibromido{2-[(4-nitro-phen-yl)imino-meth-yl]pyridine-κN,N'}zinc(II).

Project description:In the title compound, [ZnBr(2)(C(12)H(9)N(3)O(2))], the Zn(II) ion is bonded to two Br ions and two N atoms of the diimine ligand in a distorted tetra-hedral geometry. With the exception of the Br atoms, all other atoms are disordered over two sets of sites corresponding to a 180° rotation of the mol-ecule along [[Formula: see text]02]. The refined occupancies of the components are 0.809 (2) and 0.191 (2). In addition, the crystal studied was a non-merohedral twin with a refined component ratio of 0.343 (2):0.657 (2).

| S-EPMC3246977 | biostudies-literature

Dibromido{2-[(4-fluoro-phen-yl)imino-meth-yl]pyridine-?(2)N,N'}zinc.

Project description:In the title complex, [ZnBr(2)(C(12)H(9)FN(2))], the Zn(II) atom has a distorted tetra-hedral Br(2)N(2) coordination sphere. The organic ligand is bidentate, coordinating the Zn(II) atom via two imine N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 10.49?(1)°. In the crystal, weak C-H?F and C-H?Br hydrogen bonds are observed.

| S-EPMC3414158 | biostudies-literature

{2-[(4-Bromo-phen-yl)imino-meth-yl]pyridine-κN,N'}diiodidozinc(II).

Project description:In the title compound, [ZnI(2)(C(12)H(9)BrN(2))], the metal centre displays a moderately distorted tetra-hedral coordination geometry defined by two iodide anions and two N atoms of the organic ligand. The dihedral angle between the pyridine and benzene rings is 15.15 (13)°.

| S-EPMC2961941 | biostudies-literature

Dibromido{2-[1-(cyclo-propyl-imino)-eth-yl]pyridine}-zinc(II).

Project description:In the title compound, [ZnBr(2)(C(10)H(12)N(2))], the Zn(2+) ion is coordinated by the N,N'-bidentate Schiff base ligand and two bromode ions in a distorted tetra-hedral arrangement. The dihedral angle between the pyridine and the cyclo-propyl rings is 95.4?(8)°.

| S-EPMC3007484 | biostudies-literature

Di-?-chlorido-bis-({2-[(4-bromo-phen-yl)-imino-meth-yl]pyridine-?N,N'}-chloridomercury(II)).

Project description:The unique Hg(II) ion in the title centrosymmetric dinuclear complex, [Hg(2)Cl(4)(C(12)H(9)BrN(2))(2)], is in a distorted trigonal-bipyramidal coordination environment formed by the bis-chelating N-heterocyclic ligand, two bridging Cl atoms and one terminal Cl atom. One of the bridging Hg-Cl bonds is significantly longer than the other.

| S-EPMC2977257 | biostudies-literature

Dibromido{2-[2-(piperidinium-1-yl)ethyl-imino-meth-yl]phenolato}zinc(II) monohydrate.

Project description:The asymmetric unit of the title compound, [ZnBr(2)(C(14)H(20)N(2)O)]·H(2)O, consists of a mononuclear Schiff base zinc(II) complex mol-ecule and a solvent water mol-ecule. The Zn(II) atom is four-coordinated in an approximately tetra-hedral geometry, binding to the imine N and phenolate O atoms of the neutral zwitterionic Schiff base ligand and to two terminal Br(-) anions. In the crystal structure, mol-ecules are linked through inter-molecular O-H⋯Br and O-H⋯O hydrogen bonds, forming chains running along the b axis.

| S-EPMC2961651 | biostudies-literature

Diiodido{2-[(4-meth-oxy-phen-yl)imino-meth-yl]pyridine-?(2)N,N'}zinc.

Project description:In the title complex, [ZnI(2)(C(13)H(12)N(2)O)], the Zn(II) atom has a distorted tetra-hedral coordination. The organic ligand is bidentate, coordinating the Zn(II) atom via the two N atoms. The benzene and pyridine rings are oriented at a dihedral angle of 11.67?(9)°. In the crystal, weak C-H?I and C-H?O hydrogen bonds are observed, in addition to ?-? stacking inter-actions, with a centroid-centroid distance of 3.72?(5)?Å.

| S-EPMC3414111 | biostudies-literature

Dichlorido{2-[(2,6-dimethyl-phen-yl)imino-meth-yl]pyridine-?N,N'}zinc.

Project description:In the asymmetric unit of the title compound, [ZnCl(2)(C(14)H(14)N(2))], the central Zn(II) ion is four-coordinated in a distorted tetra-hedral environment by two N atoms of the ligand 2-[(2,6-dimethyl-phen-yl)imino-meth-yl]pyridine and two chloride anions. In the crystal, adjacent mol-ecules are connected through C-H?Cl hydrogen bonds between a C-H group of the ligand and a Cl(-) anion, leading to a chain-like structure along the b direction.

| S-EPMC3297262 | biostudies-literature

4-Bromo-2-({4-[(hy-droxy-imino)-meth-yl]phen-yl}imino-meth-yl)phenol.

Project description:In the title compound, C(14)H(11)BrN(2)O(2), the mean planes of the two benzene rings are almost parallel to each other, making a dihedral angle of 4.09?(1)°. An intra-molecular O-H?N hydrogen bond occurs. In the crystal, inter-molecular O-H?N and C-H?O hydrogen bonds link the mol-ecules into a chain-like supra-molecular structure.

| S-EPMC3007216 | biostudies-literature

2-[(3-Bromo-phen-yl)imino-meth-yl]phenol.

Project description:The title compound, C(13)H(10)BrNO, was prepared by reaction of 3-bromo-aniline with 2-hydroxy-benzaldehyde at 377?K. The mol-ecular structure and packing are stabilized by an intra-molecular O-H?N hydrogen-bond inter-action.

| S-EPMC2960578 | biostudies-literature

OmicsDI is part of the ELIXIR infrastructure

OmicsDI is an Elixir interoperability service. Learn more ›

Tweets

OmicsDI Databases

PRIDE
PeptideAtlas
MassIVE
JPOST Repository
Physiome Model Repository

EGA
EVA
ENA
LINCS
PAXDB
Cell Collective

MetaboLights
Metabolomics Workbench
MetabolomeExpress
GNPS
BioModels
FAIRDOMHub

ArrayExpress
dbGaP
ExpressionAtlas
GEO
NODE

Information

Databases
Help
API
Contact us
Code on GitHub
Terms of use
Submit Data