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Tetra-ethyl-ammonium tricarbonyl-chlorido(quinoxaline-2-carboxyl-ato-?N,O)rhenate(I).

ABSTRACT: In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C-H?O hydrogen bonding and ?-? stacking inter-actions involving the benzene rings, with a centroid-centroid distance of 3.4220?(1)?Å.

SUBMITTER: Suthiram J

PROVIDER: S-EPMC3007518 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Tetra-ethyl-ammonium tricarbonyl-chlorido(quinoxaline-2-carboxyl-ato-κN,O)rhenate(I).

Suthiram Janine J Zeevaart Jan Rijn JR Visser Hendrik G HG Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20100731 Pt 8

In the title compound, (C(8)H(20)N)[Re(C(9)H(5)N(2)O(2))Cl(CO)(3)], the Re(I) atom is coordinated facially by three carbonyl groups, the bidentate quinoxaline-2-carbaldehyde ligand and a chloride atom, forming a distorted octahedral geometry.. The crystal packing is controlled by C-H⋯O hydrogen bonding and π-π stacking inter-actions involving the benzene rings, with a centroid-centroid distance of 3.4220 (1) Å. ...[more]

PMID: 21588112

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