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Triethyl-ammonium tetra-chlorido(pyridine-2-carboxyl-ato-?N,O)stannate(IV).

ABSTRACT: The cation and the anion in the title salt, (C(6)H(16)N)[SnCl(4)(C(6)H(4)NO(2))], are linked by an N-H?O hydrogen bond. The Sn(IV) atom in the stannate anion is chelated by the pyridine-2-carboxyl-ate group and exists in a cis-SnCl(4)NO octa-hedral geometry. The cation is disordered over two positions in a 0.564?(1):0.436?(1) ratio.

SUBMITTER: Najafi E

PROVIDER: S-EPMC3052166 | biostudies-literature | 2011 Feb

REPOSITORIES: biostudies-literature

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Triethyl-ammonium tetra-chlorido(pyridine-2-carboxyl-ato-κN,O)stannate(IV).

Najafi Ezzatollah E Amini Mostafa M MM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20110219 Pt 3

The cation and the anion in the title salt, (C(6)H(16)N)[SnCl(4)(C(6)H(4)NO(2))], are linked by an N-H⋯O hydrogen bond. The Sn(IV) atom in the stannate anion is chelated by the pyridine-2-carboxyl-ate group and exists in a cis-SnCl(4)NO octa-hedral geometry. The cation is disordered over two positions in a 0.564 (1):0.436 (1) ratio. ...[more]

PMID: 21522280

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