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Poly[(?(4)-1,2,3-benzothia-diazole-7-carboxyl-ato)silver(I)].

ABSTRACT: In the crystal structure of the title compound, [Ag(C(7)H(3)N(2)O(2)S)](n), the Ag(I) atom is coordinated by two N atoms and three O atoms of four organic ligands forming a distorted square pyramid. The carboxyl-ate group acts as a bidentate ligand on one Ag(I) atom and as a bridging group for a symmetry-related Ag(I) atom, forming a dimer. Futhermore, the two N atoms of two thia-diazole rings bridge a third symmetry-related Ag(I) atom, forming a six-membered ring. These two frameworks, AgO(2)Ag and AgN(4)Ag, extend in three directions, forming a three-dimensionnal polymer. The whole polymer is organized around inversion centers.

SUBMITTER: Zhao JP

PROVIDER: S-EPMC3007519 | biostudies-literature | 2010 Jul

REPOSITORIES: biostudies-literature

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Poly[(μ(4)-1,2,3-benzothia-diazole-7-carboxyl-ato)silver(I)].

Zhao Jiong-Peng JP Liu Fu-Chen FC

Acta crystallographica. Section E, Structure reports online 20100721 Pt 8

In the crystal structure of the title compound, [Ag(C(7)H(3)N(2)O(2)S)](n), the Ag(I) atom is coordinated by two N atoms and three O atoms of four organic ligands forming a distorted square pyramid. The carboxyl-ate group acts as a bidentate ligand on one Ag(I) atom and as a bridging group for a symmetry-related Ag(I) atom, forming a dimer. Futhermore, the two N atoms of two thia-diazole rings bridge a third symmetry-related Ag(I) atom, forming a six-membered ring. These two frameworks, AgO(2)Ag ...[more]

PMID: 21588198

Similar Datasets

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