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Tricarbon-yl[?-2-(methyl-diphenyl-phosphanium-yl)-1,3,4-triphenylcyclo-penta-dienyl]molybdenum(0).

ABSTRACT: The title compound, [Mo(C(36)H(29)P)(CO)(3)], contains an Mo(0) atom with a typical piano-stool coordination defined by the phospho-nium cyclo-penta-dienylide ligand ?(5)-1-(methyl-diphenyl-phosphanium-yl)-2,3,5-triphenyl-2,4-cyclo-penta-dien-1-yl and by three carbonyl groups. The distance between the Mo(0) atom and the cyclo-penta-dienyl ring is 2.0616?(13)?Å.

SUBMITTER: Xu T

PROVIDER: S-EPMC3009153 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Tricarbon-yl[η-2-(methyl-diphenyl-phosphanium-yl)-1,3,4-triphenylcyclo-penta-dienyl]molybdenum(0).

Xu Tao T Ye Junwei J Gong Weitao W Lin Yuan Y Ning Guiling G

Acta crystallographica. Section E, Structure reports online 20101013 Pt 11

The title compound, [Mo(C(36)H(29)P)(CO)(3)], contains an Mo(0) atom with a typical piano-stool coordination defined by the phospho-nium cyclo-penta-dienylide ligand η(5)-1-(methyl-diphenyl-phosphanium-yl)-2,3,5-triphenyl-2,4-cyclo-penta-dien-1-yl and by three carbonyl groups. The distance between the Mo(0) atom and the cyclo-penta-dienyl ring is 2.0616 (13) Å. ...[more]

PMID: 21588827

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