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Chlorido(?-cyclo-octa-1,5-diene)(N,N'-diethyl-thio-urea-?S)rhodium(I).

ABSTRACT: In the title rhodium(I) complex, [RhCl(C(8)H(12))(C(5)H(12)N(2)S)], N,N'-diethyl-thio-urea acts as a monodenate S-donor ligand. The rhodium(I) coordination sphere is completed by the Cl atom and the COD [= 1,5-cyclo-octa-diene] ligand inter-acting through the ?-electrons of the double bonds. If the midpoints of these two bonds are taken into account, the Rh atom exhibits a distorted square-planar coordination. The syn conformation of the N,N'-diethyl-thio-urea ligand with respect to the Cl atom is stabilized by an intra-molecular N-H?Cl hydrogen bond. A weak inter-molecular N-H?Cl inter-action links mol-ecules along the a axis.

SUBMITTER: Brancatelli G

PROVIDER: S-EPMC3009226 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Chlorido(η-cyclo-octa-1,5-diene)(N,N'-diethyl-thio-urea-κS)rhodium(I).

Brancatelli Giovanna G Drommi Dario D Bruno Giuseppe G Faraone Felice F

Acta crystallographica. Section E, Structure reports online 20101009 Pt 11

In the title rhodium(I) complex, [RhCl(C(8)H(12))(C(5)H(12)N(2)S)], N,N'-diethyl-thio-urea acts as a monodenate S-donor ligand. The rhodium(I) coordination sphere is completed by the Cl atom and the COD [= 1,5-cyclo-octa-diene] ligand inter-acting through the π-electrons of the double bonds. If the midpoints of these two bonds are taken into account, the Rh atom exhibits a distorted square-planar coordination. The syn conformation of the N,N'-diethyl-thio-urea ligand with respect to the Cl atom ...[more]

PMID: 21588809

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Dichlorido(?-cyclo-octa-1,5-diene)bis-(triphenyl-phosphine)osmium(II).

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