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(N-Benzoyl-N',N'-diphenyl-thio-ureato-?(2)S,O)(?(4)-cyclo-octa-1,5-diene)rhodium(I).

ABSTRACT: The title complex, [Rh(C(20)H(15)N(2)OS)(C(8)H(12))], exhibits an essentially square-planar coordination environment around the Rh(I) atom, which bears a bidentate cyclo-octa-diene ligand as well as a monoanionic bidentate benzoyl-thio-ureate ligand. The Rh(I) atom, the S- and O-donor atoms and the alkene centroids of the cyclo-octa-diene ligand do not deviate by more than 0.031?Å from their least mean-squares plane.

SUBMITTER: Warsink S

PROVIDER: S-EPMC3414120 | biostudies-literature | 2012 Aug

REPOSITORIES: biostudies-literature

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(N-Benzoyl-N',N'-diphenyl-thio-ureato-κ(2)S,O)(η(4)-cyclo-octa-1,5-diene)rhodium(I).

Warsink Stefan S Roodt Andreas A

Acta crystallographica. Section E, Structure reports online 20120710 Pt 8

The title complex, [Rh(C(20)H(15)N(2)OS)(C(8)H(12))], exhibits an essentially square-planar coordination environment around the Rh(I) atom, which bears a bidentate cyclo-octa-diene ligand as well as a monoanionic bidentate benzoyl-thio-ureate ligand. The Rh(I) atom, the S- and O-donor atoms and the alkene centroids of the cyclo-octa-diene ligand do not deviate by more than 0.031 Å from their least mean-squares plane. ...[more]

PMID: 22904727

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(N-Benzoyl-N'-phenyl-thio-urea-?S)chlorido(?-1,5-cyclo-octa-diene)rhodium(I).

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