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Tribenzylbis(triphenyl-arsine oxide-?O)tin(IV) tetra-phenyl-borate.

ABSTRACT: The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C-Sn-C angles 360.0?(3)° and O-Sn-O angle 173.1?(1)°]. The structure contains voids of 113?(19)?Å(3), but no solvent mol-ecule could reasonably be located there.

SUBMITTER: Keng TC

PROVIDER: S-EPMC3009232 | biostudies-literature | 2010 Oct

REPOSITORIES: biostudies-literature

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Tribenzylbis(triphenyl-arsine oxide-κO)tin(IV) tetra-phenyl-borate.

Keng Thy Chun TC Lo Kong Mun KM Ng Seik Weng SW

Acta crystallographica. Section E, Structure reports online 20101009 Pt 11

The crystal structure of the title salt, [Sn(C(7)H(7))(3)(C(18)H(15)AsO)(2)][B(C(6)H(5))(4)], consists of discrete cations and anions; the tin atom of the cation is five-coordinated in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry [summation of C-Sn-C angles 360.0 (3)° and O-Sn-O angle 173.1 (1)°]. The structure contains voids of 113 (19) Å(3), but no solvent mol-ecule could reasonably be located there. ...[more]

PMID: 21588813

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