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Catena-Poly[[diaqua-cobalt(II)]bis-[?-2-(4-carboxyl-atophen-yl)-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide]].

ABSTRACT: In the title compound, [Co(C(14)H(16)N(2)O(4))(2)(H(2)O)(2)](n), the Co(II) atom, lying on an inversion center, is coordinated by six O atoms in a distorted octa-hedral geometry. The Co(II) atoms are bridged by the nitronyl nitroxide ligands into a tape-like structure along the b axis. The tapes are further connected by O-H?O hydrogen bonds, forming a layer parallel to the bc plane.

SUBMITTER: Rong R

PROVIDER: S-EPMC3099874 | biostudies-other | 2011 Apr

REPOSITORIES: biostudies-other

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catena-Poly[[diaqua-cobalt(II)]bis-[μ-2-(4-carboxyl-atophen-yl)-4,4,5,5-tetra-methyl-4,5-dihydro-1H-imidazol-1-oxyl 3-oxide]].

Rong Rong R Gao Ge G Zhu Lili L

Acta crystallographica. Section E, Structure reports online 20110326 Pt 4

In the title compound, [Co(C(14)H(16)N(2)O(4))(2)(H(2)O)(2)](n), the Co(II) atom, lying on an inversion center, is coordinated by six O atoms in a distorted octa-hedral geometry. The Co(II) atoms are bridged by the nitronyl nitroxide ligands into a tape-like structure along the b axis. The tapes are further connected by O-H⋯O hydrogen bonds, forming a layer parallel to the bc plane. ...[more]

PMID: 21753999

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