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[2-Hydroxy-N'-(4-oxo-4-phenyl-butan-2-yl-idene)benzohydrazidato(2-)]pyridine-copper(II).

ABSTRACT: The mononuclear title complex, [Cu(C(17)H(14)N(2)O(3))(C(5)H(5)N)], was synthesized by the reaction of CuCl(2)·2H(2)O with N-(4-oxo-4-phenyl-butan-2-yl-idene)benzohydrazide (H(2)L). The central Cu(II) atom exhibits a distorted square-planar coordination geometry, defined by two O atoms, one N atom from the ligand and one pyridine N atom with Cu-N distances of 1.874?(4) and 1.963?(4)?Å, while the Cu-O distances are 1.857?(3) and 1.890?(3)?Å. An intra-molecular O-H?N inter-action occurs.

SUBMITTER: Zhang SP

PROVIDER: S-EPMC3011487 | biostudies-literature | 2010 Nov

REPOSITORIES: biostudies-literature

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[2-Hydroxy-N'-(4-oxo-4-phenyl-butan-2-yl-idene)benzohydrazidato(2-)]pyridine-copper(II).

Zhang Shu-Ping SP Wei Ying Y Shao Si-Chang SC

Acta crystallographica. Section E, Structure reports online 20101124 Pt 12

The mononuclear title complex, [Cu(C(17)H(14)N(2)O(3))(C(5)H(5)N)], was synthesized by the reaction of CuCl(2)·2H(2)O with N-(4-oxo-4-phenyl-butan-2-yl-idene)benzohydrazide (H(2)L). The central Cu(II) atom exhibits a distorted square-planar coordination geometry, defined by two O atoms, one N atom from the ligand and one pyridine N atom with Cu-N distances of 1.874 (4) and 1.963 (4) Å, while the Cu-O distances are 1.857 (3) and 1.890 (3) Å. An intra-molecular O-H⋯N inter-action occurs. ...[more]

PMID: 21589308

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